Art

J-GLOBAL ID：200902138322655995   Reference number：02A0195578

Stereoselective Synthesis of Cyclic Ethers by SmI₂-Induced Reductive Intramolecular Cyclization.

SmI₂誘起還元的分子内環化による環状エーテルの立体選択的合成

Author (3)： MATSUO G (RIKEN (Inst. Physical and Chemical Res.), Saitama) ,  KADOHAMA H (RIKEN (Inst. Physical and Chemical Res.), Saitama) ,  NAKATA T (RIKEN (Inst. Physical and Chemical Res.), Saitama)
Material： Chemistry Letters  (Chem Lett)
Issue： 2  Page： 148-149  Publication year： Feb. 05, 2002 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,...
Semi thesaurus term： samarium diiodide

   To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=02A0195578&from=J-GLOBAL&jstjournalNo=S0742A") }}

JST classification (1)： Oxygen heterocycles in general  (CF07020K)

Substance index (17)： γ-Decalactone ,  3-[[1-(3-Oxopropyl)heptyl]oxy]acrylic acid ethyl ester ,  3β-Hydroxy-6α-hexyltetrahydro-2H-pyran-2α-acetic acid ethyl ester ,  5-Undecanolide ,  3-[[1-(4-Oxobutyl)heptyl]oxy]acrylic acid ethyl ester ,  3aα,5,6,7,8,8aβ-Hexahydro-5β-hexylfuro[3,2-b]oxepin-2(3H)-one ,  (2R)-1,2-Epoxyoctane ,  3-[[(R)-1-(2-Oxoethyl)heptyl]oxy]acrylic acid ethyl ester ,  3α-Hydroxy-5β-hexyltetrahydrofuran-2β-acetic acid ethyl ester ,  3β-Hydroxy-5β-hexyltetrahydrofuran-2β-acetic acid ethyl ester ,  3-[[1-(5-Oxopentyl)heptyl]oxy]acrylic acid ethyl ester ,  3,3aα,5,6,7,8,9,9aβ-Octahydro-5β-hexyl-2H-furo[3,2-b]oxocin-2-one ,  3,3aα,5,6,7,8,9,9aα-Octahydro-5β-hexyl-2H-furo[3,2-b]oxocin-2-one ,  3,3aβ,5,6,7,8,9,9aβ-Octahydro-5β-hexyl-2H-furo[3,2-b]oxocin-2-one ,  3-[[(R)-1-Hexyl-6-oxo-3-hexenyl]oxy]acrylic acid ethyl ester ,  3,3aβ,5,6,9,9aα-Hexahydro-5α-hexyl-2H-furo[3,2-b]oxocin-2-one ,  3,3aβ,5,6,9,9aβ-Hexahydro-5α-hexyl-2H-furo[3,2-b]oxocin-2-one

Reference (14)：

• 1) For reviews, see: a) R. E. Moore, “Marine Natural Products;” ed. by P. J. Scheuer, Academic Press, New York (1978), Vol. 1, p 43.
•  b) K. L. Erickson, “Marine Natural Products;” ed. by P. J. Scheuer, Academic Press, New York (1983), Vol. 5, p 131.
•  c) T. Yasumoto and M. Murata, Chem. Rev., 93, 1897 (1993).
• 2) a) N. Hori, H. Matsukura, G. Matsuo, and T. Nakata, Tetrahedron Lett., 40, 2811 (1999).
•  b) N. Hori, H. Matsukura, and T. Nakata, Org. Lett., 1, 1099 (1999).

Terms in the title (5)： 誘起 ,  還元 ,  分子内環化 ,  環状エーテル ,  立体選択的合成