Art

J-GLOBAL ID：200902140613541614   Reference number：02A0648311

Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with 1-Alkenyl Halides or Triflates: Convenient Synthesis of Unsymmetrical 1,3-Dienes via the Borylation-Coupling Sequence.

ビス(ピナコラト)ジボロンと1-アルケニルハロゲン化物またはトリフラートとのパラジウム触媒による交差カップリング反応 ボリル化-カップリングシーケンスによる非対称1,3-ジエン類の簡便合成

Author (4)： TAKAGI J (Hokkaido Univ., Sapporo, JPN) ,  TAKAHASHI K (Hokkaido Univ., Sapporo, JPN) ,  ISHIYAMA T (Hokkaido Univ., Sapporo, JPN) ,  MIYAURA N (Hokkaido Univ., Sapporo, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 124  Issue： 27  Page： 8001-8006  Publication year： Jul. 10, 2002 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...
Semi thesaurus term： triflate

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JST classification (2)： Organoboron compounds  (CF08020R) ,  Alkenes  (CF03030T)

Substance index (57)： Bis(pinacolato)diboron ,  2-(1-Octylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-Iodo-1-decene ,  2-Bromo-1-decene ,  2-(Trifluoromethylsulfonyloxy)-1-decene ,  2-Bromo-3,3-dimethyl-1-butene ,  2-(Trifluoromethylsulfonyloxy)-3,3-dimethyl-1-butene ,  α-Bromostyrene ,  α-(Trifluoromethylsulfonyloxy)styrene ,  1-Bromo-2-methyl-1-propene ,  (E)-1-Bromo-1-decene ,  (Z)-1-Bromo-1-decene ,  2-Bromo-4-(tert-butyldimethylsiloxy)-5-methyl-1-hexene ,  2-Bromo-5-chloro-1-pentene ,  5-Bromo-5-hexenenitrile ,  3-(Trifluoromethylsulfonyloxy)isocrotonic acid ethyl ester ,  2-[1-(1,1-Dimethylethyl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(1-Phenylvinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-Isobutenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-[(E)-1-Decenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-[(Z)-1-Decenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-[1-Methylene-3-(tert-butyldimethylsiloxy)-4-methylpentyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(1-Methylene-4-chlorobutyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(1-Methylene-4-cyanobutyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  (E)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-2-butenoic acid ethyl ester ,  1-Iodocyclohexene ,  1-Bromo-1-cyclohexene ,  Cyclohexene-1-ol trifluoromethanesulfonate ,  4-tert-Butylcyclohexene-1-ol trifluoromethanesulfonate ,  1-(Trifluoromethylsulfonyloxy)-2,6-dimethyl-1-cyclohexene ,  2-(Trifluoromethylsulfonyloxy)-1,3-cyclohexadiene ,  1-(Trifluoromethylsulfonyloxy)-2-methyl-1-cyclohexene ,  1-(Trifluoromethylsulfonyloxy)-6-methyl-1-cyclohexene ,  1-(Trifluoromethylsulfonyloxy)-1-cyclopentene ,  1-(Trifluoromethylsulfonyloxy)-1-cycloheptene ,  1-(Trifluoromethylsulfonyloxy)-1-cyclooctene ,  2-(1-Cyclohexenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(4-tert-Butyl-1-cyclohexenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(2,6-Dimethyl-1-cyclohexenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(1,5-Cyclohexadienyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(2-Methyl-1-cyclohexenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(6-Methyl-1-cyclohexenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(1-Cyclopentenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(1-Cycloheptenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(1-Cyclooctenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  3β-(tert-Butyldimethylsiloxy)-20-(trifluoromethylsulfonyloxy)pregna-5,20-diene ,  3-(tert-Butyldimethylsiloxy)-17-(trifluoromethylsulfonyloxy)estra-1,3,5(10),16-tetrene ,  3β-(tert-Butyldimethylsiloxy)-20-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)pregna-5,20-diene ,  3-(tert-Butyldimethylsiloxy)-17-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)estra-1,3,5(10),16-tetrene ,  1-(1-Methylenenonyl)-1-cyclohexene ,  1-(1-Methylenenonyl)-1-cyclopentene ,  9,10-Dimethyleneoctadecane ,  1-(1-Cyclopentenyl)-1-cyclohexene ,  1-(1-Cyclopentenyl)-4-tert-butyl-1-cyclohexene ,  2-Methyl-1,1′-bi[1-cyclohexene] ,  6-Methyl-1,1′-bi[1-cyclohexene] ,  (αE)-β,2-Dimethyl-3-oxo-1-cyclohexene-1-acrylic acid ethyl ester

Terms in the title (10)： ビス ,  トリフラート ,  パラジウム触媒 ,  交差カップリング反応 ,  ボリル化 ,  カップリング ,  シーケンス ,  非対称 ,  ジエン類 ,  簡便