Art

J-GLOBAL ID：200902143149053252   Reference number：99A0243919

Asymmetric Hydrogenation of Alkenyl, Cyclopropyl, and Aryl Ketones. RuCl₂(xylbinap)(1,2-diamine) as a Precatalyst Exhibiting a Wide Scope.

アルケニル,シクロプロピル及びアリールケトンの不斉水素化 広範な適用性を示す触媒前駆体としてのRuCl₂(xylbinap)(1,2-ジアミン)

Author (9)： OHKUMA T (Nagoya Univ., Nagoya, JPN) ,  KOIZUMI M (Nagoya Univ., Nagoya, JPN) ,  DOUCET H (Nagoya Univ., Nagoya, JPN) ,  PHAM T (Nagoya Univ., Nagoya, JPN) ,  KOZAWA M (Japan Sci. and Technol. Corp., Toyota, JPN) ,  MURATA K (Japan Sci. and Technol. Corp., Toyota, JPN) ,  KATAYAMA E (Japan Sci. and Technol. Corp., Toyota, JPN) ,  YOKOZAWA T (Japan Sci. and Technol. Corp., Toyota, JPN) ,  NOYORI R (Nagoya Univ., Nagoya, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 120  Issue： 51  Page： 13529-13530  Publication year： Dec. 30, 1998 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (2)： Aliphatic ketones  (CF03190Q) ,  Platinum family element complexes  (CE01100E)

Substance index (45)： Methyl ((E)-styryl) ketone ,  (E)-1-Phenyl-4-methyl-1-penten-3-one ,  (E)-3-Nonen-2-one ,  (E)-6-Methyl-2-hepten-4-one ,  4-Methyl-3-penten-2-one ,  1-Acetyl-1-cyclohexene ,  1-Acetylcycloheptene ,  1-Acetyl-2-methyl-1-cyclopentene ,  2,2′-Bis[bis(3,5-xylyl)phosphino]-1,1′-binaphthalene ,  (2S)-1,1-Di(4-methoxyphenyl)-2-isopropylethylenediamine ,  1α,2β-Cyclohexanediamine ,  (-)-Stilbenediamine ,  (+)-Methylstyrylcarbinol ,  (1E,3R)-1-Phenyl-4-methyl-1-pentene-3-ol ,  (R,E)-3-Nonene-2-ol ,  (2E,4R)-6-Methyl-2-heptene-4-ol ,  (R)-4-Methyl-3-pentene-2-ol ,  (R)-1-(1-Cyclohexenyl)ethanol ,  (1R)-1-(1-Cycloheptene-1-yl)ethanol ,  (R)-1-(2-Methyl-1-cyclopentenyl)ethanol ,  Methyl cyclopropyl ketone ,  Phenyl cyclopropyl ketone ,  1-Cyclopropylethanol ,  α-Cyclopropylbenzyl alcohol ,  (R)-1-Phenylethanol ,  (R)-1-(m-Tolyl)ethanol ,  (1R)-1-(2-Trifluoromethylphenyl)ethanol ,  (1R)-1-(4-Chlorophenyl)-1-propanol ,  (R)-1-(p-Bromophenyl)ethanol ,  (R)-1-(p-Chlorophenyl)ethanol ,  (R)-1-(4-Trifluoromethylphenyl)ethanol ,  (R)-α-Methyl-4-methoxybenzyl alcohol ,  4-[(R)-1-Hydroxyethyl]benzoic acid isopropyl ester ,  (R)-1-(4-Nitrophenyl)ethanol ,  (R)-1-(4-Aminophenyl)ethanol ,  α,α,α-Trifluoroacetophenone ,  α,α,α-Trifluoro-4′-chloroacetophenone ,  α,α,α-Trifluoro-4′-bromoacetophenone ,  1-Methoxy-4-(trifluoroacetyl)benzene ,  (1S)-1-Phenyl-2,2,2-trifluoroethanol ,  (S)-1-(4-Chlorophenyl)-2,2,2-trifluoroethanol ,  (S)-1-(4-Bromophenyl)-2,2,2-trifluoroethanol ,  (S)-1-(4-Methoxyphenyl)-2,2,2-trifluoroethanol ,  (S)-1-Phenylethanol ,  (S)-1-[2-(Trifluoromethyl)phenyl]ethanol

Terms in the title (5)： アリールケトン ,  不斉水素化 ,  適用性 ,  触媒前駆体 ,  ジアミン