Art

J-GLOBAL ID：200902145793011695   Reference number：00A0974689

Absolute Configuration at C45 in 45-Hydroxyyessotoxin, a Marine Polyether Toxin Isolated from Shellfish.

二枚貝より単離したポリエーテル毒45-Hydroxyyessotoxinの45位の絶対配置決定

Author (4)： MOROHASHI A (Tohoku Univ., Sendai, JPN) ,  SATAKE M (Tohoku Univ., Sendai, JPN) ,  OSHIMA Y (Tohoku Univ., Sendai, JPN) ,  YASUMOTO T (Tohoku Univ., Sendai, JPN)
Material： Bioscience, Biotechnology, and Biochemistry  (Bioscience Biotechnology & Biochemistry)
Volume： 64  Issue： 8  Page： 1761-1763  Publication year： Aug. 23, 2000 
JST Material Number： G0021A  ISSN： 0916-8451  CODEN： BBBIEJ  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： Bivalvia ,...

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JST classification (2)： Animal biochemistry  (EJ01050P) ,  Other natural substances of biological origin  (CF10090R)

Substance index (4)： Yessotoxin ,  (3R,4S,6R,7S,9R,10S,12R,13S,15R,16S,19R,20S,22R,23S,26S,27R,28S,30R,31S,32R,33S,34S,36R,37S,40S,41R,42E,45R)-3,19,23,26,33,41-Hexamethyl-39,44-bismethylene-3,7:6,10:9,13:12,16:15,20:19,23:22,28:27,31:30,34:33,37:36,40-undecaepoxyheptatetracontane-42,46-diene-1,4,32,41,45-pentol 1,4-bis(sulfuric acid sodium) salt ,  (3R,4S,6R,7S,9R,10S,12R,13S,15R,16S,19R,20S,22R,23S,26S,27R,28S,30R,31S,32R,33S,34S,36R,37S,40S,41R,42E,45R)-3,19,23,26,33,41-Hexamethyl-39,44-bismethylene-3,7:6,10:9,13:12,16:15,20:19,23:22,28:27,31:30,34:33,37:36,40-undecaepoxyheptatetracontane-42,46-diene-1,4,32,41,45-pentol 1,4-bis(sulfuric acid sodium)45-[(S)-2-methoxy-2-(trifluoromethyl)-2-phenylacetate] salt ,  (3R,4S,6R,7S,9R,10S,12R,13S,15R,16S,19R,20S,22R,23S,26S,27R,28S,30R,31S,32R,33S,34S,36R,37S,40S,41R,42E,45R)-3,19,23,26,33,41-Hexamethyl-39,44-bismethylene-3,7:6,10:9,13:12,16:15,20:19,23:22,28:27,31:30,34:33,37:36,40-undecaepoxyheptatetracontane-42,46-diene-1,4,32,41,45-pentol 1,4-bis(sulfuric acid sodium)45-[(R)-2-methoxy-2-(trifluoromethyl)-2-phenylacetate] salt

Reference (14)：

• 1) Yasumoto, T. and Murata, M., Marine toxins. Chem. Rev., 93, 1897-1909 (1993).
• 2) Satake, M., Morohashi, A., Oguri, H., Oishi, T., Hirama, M., Harada, N., and Yasumoto, T., The absolute configuration of ciguatoxin. J. Am. Chem. Soc., 119, 11325-11326 (1997).
• 3) Nonomura, T., Sasaki, M., Matsumori, N., Murata, M., Tachibana K., and Yasumoto, T., The complete structure of maitotoxin, II; configuration of the C135-C142 side chain and absolute configuration of the entire molecule. Angew. Chem. Int. Ed. Engl., 35, 1675-1678 (1996).
• 4) Sasaki, K., Satake, M., and Yasumoto, T., Identification of the absolute configuration of pectenotoxin-6, a polyether macrolide compound, by NMR spectroscopic method using a chiral anisotropic reagent, phenylglycine methyl ester. Biosci. Biotechnol. Biochem., 61, 1783-1785 (1997).
• 5) Sasaki, K., Onodera, H., and Yasumoto, T., Application of the phenylglycine methyl ester to the establishment of the absolute configuration of dinophysistoxin-1, a polyether toxin responsible for diarrhetic shellfish poisoning. Enantiomer, 3, 59-63 (1998).

Terms in the title (4)： 二枚貝 ,  単離 ,  ポリエーテル ,  毒