Art

J-GLOBAL ID：200902150393425346   Reference number：00A0173451

A novel tandem [4⁺+2] cycloaddition-elimination reaction of 4,4-dimethyl-2-styryl-1,3-oxathianes with olefins.

4,4-ジメチル-2-スチリル-1,3-オキサチアン類とオレフィンの新規な逐次[4⁺+2]環状付加-脱離反応

Author (3)： NISHIDE K (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  OHSUGI S (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  NODE M (Kyoto Pharmaceutical Univ., Kyoto, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 41  Issue： 3  Page： 371-375  Publication year： Jan. 15, 2000 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *cycloaddition ,...

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JST classification (1)： Dioxanes,oxathians,dithians  (CF07099G)

Substance index (27)： (2R)-4,4-Dimethyl-2β-styryl-1,3-oxathiane ,  (2R)-4,4-Dimethyl-2β-(4-methoxystyryl)-1,3-oxathiane ,  1,1-Diphenylethene ,  α-Methylstyrene ,  2-Phenyl-1-butene ,  2-Phenyl-1-pentene ,  2,3-Diphenyl-1-propene ,  α-Methyl-4-bromostyrene ,  Allyltrimethylsilane ,  2,2,4-Triphenyl-3,4-dihydro-2H-thiopyran ,  rel-2α^*,4α^*-Diphenyl-2-methyl-3,4-dihydro-2H-thiopyran ,  rel-2α^*,4β^*-Diphenyl-2-methyl-3,4-dihydro-2H-thiopyran ,  rel-2α^*,4α^*-Diphenyl-2-ethyl-3,4-dihydro-2H-thiopyran ,  rel-2α^*,4β^*-Diphenyl-2-ethyl-3,4-dihydro-2H-thiopyran ,  rel-2α^*,4α^*-Diphenyl-2-propyl-3,4-dihydro-2H-thiopyran ,  rel-2α^*,4β^*-Diphenyl-2-propyl-3,4-dihydro-2H-thiopyran ,  rel-2α^*,4α^*-Diphenyl-2-benzyl-3,4-dihydro-2H-thiopyran ,  rel-2α^*,4β^*-Diphenyl-2-benzyl-3,4-dihydro-2H-thiopyran ,  3-Methyl-3-[[(1E,3R)-3-phenyl-1,5-hexadienyl]thio]-1-butanol ,  3-Methyl-3-[[(1E,3S)-3-phenyl-1,5-hexadienyl]thio]-1-butanol ,  2,2-Diphenyl-4-(4-methoxyphenyl)-3,4-dihydro-2H-thiopyran ,  rel-2α^*-Phenyl-2-methyl-4α^*-(4-methoxyphenyl)-3,4-dihydro-2H-thiopyran ,  rel-2α^*-Phenyl-2-methyl-4β^*-(4-methoxyphenyl)-3,4-dihydro-2H-thiopyran ,  rel-2α^*-Phenyl-2-propyl-4α^*-(4-methoxyphenyl)-3,4-dihydro-2H-thiopyran ,  rel-2α^*-Phenyl-2-propyl-4β^*-(4-methoxyphenyl)-3,4-dihydro-2H-thiopyran ,  rel-2α^*-(4-Bromophenyl)-2-methyl-4α^*-phenyl-3,4-dihydro-2H-thiopyran ,  rel-2α^*-(4-Bromophenyl)-2-methyl-4β^*-phenyl-3,4-dihydro-2H-thiopyran

Terms in the title (6)： ジメチル ,  オキサチアン ,  オレフィン ,  逐次 ,  環状付加 ,  脱離反応