Art

J-GLOBAL ID：200902150445395890   Reference number：01A0263945

Catalytic asymmetric borane reduction of prochiral ketones by the use of diazaborolidine catalysts prepared from chiral β-diamines.

キラルなβ-ジアミン類から調製されたジアザボロリジン触媒を使用するプロキラルなケトンの触媒的不斉ボラン還元

Author (3)： SATO S (Yokohama National Univ., Yokohama, JPN) ,  WATANABE H (Yokohama National Univ., Yokohama, JPN) ,  ASAMI M (Yokohama National Univ., Yokohama, JPN)
Material： Tetrahedron: Asymmetry  (Tetrahedron Asym)
Volume： 11  Issue： 21  Page： 4329-4340  Publication year： Nov. 03, 2000 
JST Material Number： T0907A  ISSN： 0957-4166  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： optical isomerism ,...

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JST classification (3)： Aromatic monocyclic hydroxy compounds  (CF05070Z) ,  Naphthalenes  (CF06020D) ,  Organoboron compounds  (CF08020R)

Substance index (45)： (2S)-Indoline-2α-carboxylic acid ,  (2S)-1-(tert-Butoxycarbonyl)indoline-2-carboxylic acid ,  (2S)-N-Phenyl-1-(tert-butoxycarbonyl)indoline-2α-carboxamide ,  (2S)-N-Cyclohexyl-1-(tert-butoxycarbonyl)indoline-2α-carboxamide ,  (2S)-N-(2-Methylphenyl)-1-(tert-butoxycarbonyl)indoline-2α-carboxamide ,  (2S)-N-(2,6-Dimethylphenyl)-1-(tert-butoxycarbonyl)indoline-2α-carboxamide ,  (2S)-N-(4-Methoxyphenyl)-1-(tert-butoxycarbonyl)indoline-2α-carboxamide ,  (2S)-N-[4-(Trifluoromethyl)phenyl]-1-(tert-butoxycarbonyl)indoline-2α-carboxamide ,  (2S)-N-[3,5-Bis(trifluoromethyl)phenyl]-1-(tert-butoxycarbonyl)indoline-2α-carboxamide ,  (2S)-N-(4-Nitrophenyl)-1-(tert-butoxycarbonyl)indoline-2α-carboxamide ,  (2S)-N-Phenylindoline-2α-methanamine ,  (2S)-N-Cyclohexylindoline-2α-methanamine ,  (2S)-N-(2-Methylphenyl)indoline-2α-methanamine ,  (2S)-N-(2,6-Dimethylphenyl)indoline-2α-methanamine ,  (2S)-N-(4-Methoxyphenyl)indoline-2α-methanamine ,  (2S)-N-[4-(Trifluoromethyl)phenyl]indoline-2α-methanamine ,  (2S)-N-[3,5-Bis(trifluoromethyl)phenyl]indoline-2α-methanamine ,  (2S)-N-(4-Nitrophenyl)indoline-2α-methanamine ,  Acetophenone ,  (R)-1-Phenylethanol ,  2'-Bromoacetophenone ,  α-Chloroacetophenone ,  1-Acetylnaphthalene ,  Propiophenone ,  Tetralin-1-one ,  Indan-1-one ,  2-Octanone ,  4-Phenyl-3-buten-2-one ,  (R)-1-(2-Bromophenyl)ethanol ,  (S)-1-Phenyl-2-chloroethanol ,  (R)-1-(1-Naphthyl)ethanol ,  (R)-1-Phenyl-1-propanol ,  (R)-Tetralin-1-ol ,  (R)-Indan-1-ol ,  (R)-2-Octanol ,  (2R)-4-Phenyl-3-buten-2-ol ,  (8aS)-2-Phenyl-2,3,8,8aα-tetrahydro-1H-2,3a-diaza-3-boracyclopenta[a]indene ,  (8aS)-2-Cyclohexyl-2,3,8,8aα-tetrahydro-1H-2,3a-diaza-3-boracyclopenta[a]indene ,  (8aS)-2-(2-Methylphenyl)-2,3,8,8aα-tetrahydro-1H-2,3a-diaza-3-boracyclopenta[a]indene ,  (8aS)-2-(2,6-Dimethylphenyl)-2,3,8,8aα-tetrahydro-1H-2,3a-diaza-3-boracyclopenta[a]indene ,  (8aS)-2-(4-Methoxyphenyl)-2,3,8,8aα-tetrahydro-1H-2,3a-diaza-3-boracyclopenta[a]indene ,  (8aS)-2-[4-(Trifluoromethyl)phenyl]-2,3,8,8aα-tetrahydro-1H-2,3a-diaza-3-boracyclopenta[a]indene ,  (8aS)-2-[3,5-Bis(trifluoromethyl)phenyl]-2,3,8,8aα-tetrahydro-1H-2,3a-diaza-3-boracyclopenta[a]indene ,  (8aS)-2-(4-Nitrophenyl)-2,3,8,8aα-tetrahydro-1H-2,3a-diaza-3-boracyclopenta[a]indene ,  Borane

Terms in the title (7)： キラル ,  ジアミン類 ,  調製 ,  触媒 ,  ケトン ,  ボラン ,  還元