Art

J-GLOBAL ID：200902152910549100   Reference number：02A0945723

Enantioselective Michael Additions of Nitromethane by a Catalytic Double Activation Method Using Chiral Lewis Acid and Achiral Amine Catalysts.

キラルなLewis酸及びアキラルなアミン触媒を用いた,触媒二重活性化法によるニトロメタンのエナンチオ選択的Michael付加

Author (2)： ITOH K (Kyushu Univ., Kasuga, JPN) ,  KANEMASA S (Kyushu Univ., Kasuga, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 124  Issue： 45  Page： 13394-13395  Publication year： Nov. 13, 2002 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： Lewis acid ,...

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JST classification (1)： Addition reaction,elimination reaction  (CF02030M)

Substance index (30)： Nitromethane ,  4,6-Bis(4α-phenyl-2-oxazoline-2-yl)dibenzofuran ,  1-Crotonyl-3,5-dimethyl-1H-pyrazole ,  1-(3-Methyl-4-nitrobutanoyl)-3,5-dimethyl-1H-pyrazole ,  1-Crotonoyl-3,5-dimethyl-4-bromo-1H-pyrazole ,  1-Crotonoyl-3,5-dimethyl-4-iodo-1H-pyrazole ,  1-(2-Pentenoyl)-3,5-dimethyl-1H-pyrazole ,  1-(2-Hexenoyl)-3,5-dimethyl-1H-pyrazole ,  1-(4-Methyl-2-pentenoyl)-3,5-dimethyl-1H-pyrazole ,  1-(3-Cyclohexylpropenoyl)-3,5-dimethyl-1H-pyrazole ,  1-(2-Heptenoyl)-3,5-dimethyl-1H-pyrazole ,  1-[((1E,3E)-1,3-Pentadiene-1-yl)carbonyl]-3,5-dimethyl-1H-pyrazole ,  1-(3-Methoxycarbonyl-acryloyl)-3,5-dimethyl-1H-pyrazole ,  1-(3-Phenylacryloyl)-3,5-dimethyl-1H-pyrazole ,  1-[3-(3,4-Methylenedioxyphenyl)acryloyl]-3,5-dimethyl-1H-pyrazole ,  1-[3-(Furan-2-yl)acryloyl]-3,5-dimethyl-1H-pyrazole ,  1-[3-(Thiophene-2-yl)acryloyl]-3,5-dimethyl-1H-pyrazole ,  1-(4-Nitrobutanoyl)-3,5-dimethyl-1H-pyrazole ,  1-(4-Nitrobutanoyl)-3,5-dimethyl-4-bromo-1H-pyrazole ,  1-(4-Nitrobutanoyl)-3,5-dimethyl-4-iodo-1H-pyrazole ,  1-(3-Nitromethylpentanoyl)-3,5-dimethyl-1H-pyrazole ,  1-(3-Nitromethyl-4-methylpentanoyl)-3,5-dimethyl-1H-pyrazole ,  1-(3-Nitromethylhexanoyl)-3,5-dimethyl-1H-pyrazole ,  1-(3-Cyclohexyl-4-nitrobutanoyl)-3,5-dimethyl-1H-pyrazole ,  1-[(E)-3-Nitromethyl-4-hexenoyl]-3,5-dimethyl-1H-pyrazole ,  1-(3-Methoxycarbonyl-4-nitrobutanoyl)-3,5-dimethyl-1H-pyrazole ,  1-(3-Phenyl-4-nitrobutanoyl)-3,5-dimethyl-1H-pyrazole ,  1-[3-(3,4-Methylenedioxyphenyl)-4-nitrobutanoyl]-3,5-dimethyl-1H-pyrazole ,  1-[3-(Furan-2-yl)-4-nitrobutanoyl]-3,5-dimethyl-1H-pyrazole ,  1-[3-(Thiophene-2-yl)-4-nitrobutanoyl]-3,5-dimethyl-1H-pyrazole

Terms in the title (8)： キラル ,  Lewis酸 ,  アキラル ,  アミン触媒 ,  触媒 ,  活性化法 ,  ニトロメタン ,  Michael付加