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J-GLOBAL ID：200902152946763906   Reference number：99A0841637

Highly Stereoselective Synthesis of Homoallylic Amines Based on Addition of Allyltrichlorosilanes to Benzoylhydrazones under Neutral Conditions.

中性条件下でのアリルトリクロロシランのベンゾイルヒドラゾン類への付加に基づくホモアリル性アミンの高立体選択的合成

Author (2)： KOBAYASHI S (Univ. Tokyo, Tokyo) ,  HIRABAYASHI R (Univ. Tokyo, Tokyo)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 121  Issue： 29  Page： 6942-6943  Publication year： Jul. 28, 1999 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (2)： Aliphatic amines,imines,quaternary ammonium,immonium compounds  (CF03070L) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (30)： Allyltrichlorosilane ,  ((Z)-2-Butenyl)trichlorosilane ,  ((E)-2-Butenyl)trichlorosilane ,  Trichloroprenylsilane ,  Benzaldehyde benzoylhydrazone ,  trans-Cinnamaldehyde benzoylhydrazone ,  3-Phenylpropanal benzoylhydrazone ,  Hexanal benzoyl hydrazone ,  N′-Isopentylidenebenzohydrazide ,  N′-(Cyclohexylmethylene)benzohydrazide ,  2,2-Dimethylpropanal benzoylhydrazone ,  N′-[(S)-1-Phenyl-3-butenyl]benzhydrazide ,  rel-1-[(1S^*,2S^*)-1-Phenyl-2-methyl-3-butenyl]-2-benzoylhydrazine ,  rel-1-[(1S^*,2R^*)-1-Phenyl-2-methyl-3-butenyl]-2-benzoylhydrazine ,  1-[(S)-1-[(E)-Styryl]-3-butenyl]-2-benzoylhydrazine ,  rel-1-[(1S^*,2S^*)-1-[(E)-Styryl]-2-methyl-3-butenyl]-2-benzoylhydrazine ,  rel-1-[(1S^*,2R^*)-1-[(E)-Styryl]-2-methyl-3-butenyl]-2-benzoylhydrazine ,  1-[(S)-1-[(E)-Styryl]-2,2-dimethyl-3-butenyl]-2-benzoylhydrazine ,  1-[(S)-1-Phenethyl-3-butenyl]-2-benzoylhydrazine ,  rel-1-[(1R^*,2S^*)-1-Phenethyl-2-methyl-3-butenyl]-2-benzoylhydrazine ,  rel-1-[(1R^*,2R^*)-1-Phenethyl-2-methyl-3-butenyl]-2-benzoylhydrazine ,  1-[(R)-1-Phenethyl-2,2-dimethyl-3-butenyl]-2-benzoylhydrazine ,  1-[(R)-1-Allylhexyl]-2-benzoylhydrazine ,  rel-1-[(R^*)-1-[(R^*)-1-Methyl-2-propenyl]hexyl]-2-benzoylhydrazine ,  rel-1-[(R^*)-1-[(S^*)-1-Methyl-2-propenyl]hexyl]-2-benzoylhydrazine ,  N′-[(R)-1-Isobutyl-3-butenyl]benzhydrazide ,  rel-1-[(1R^*,2S^*)-1-Isobutyl-2-methyl-3-butenyl]-2-benzoylhydrazine ,  rel-1-[(1R^*,2R^*)-1-Isobutyl-2-methyl-3-butenyl]-2-benzoylhydrazine ,  N′-[(S)-1-Cyclohexyl-3-butenyl]benzohydrazide ,  1-[(S)-1-tert-Butyl-3-butenyl]-2-benzoylhydrazine

Terms in the title (6)： 中性 ,  アリルトリクロロシラン ,  ホモ ,  アリル ,  アミン ,  立体選択的合成