Art

J-GLOBAL ID：200902153370382720   Reference number：96A0565583

Secondary and Tertiary Alcohols as Nucleophiles in the Stereospecific Synthesis of Substituted Tetrahydrofurans by Cyclisation of 1,3-Diols with Phenylsulfanyl Migration.

フェニルスルファニル移動を伴う1,3ジオールの環化による置換テトラヒドロフランの立体特異的合成での求核試薬としての第二及び第三アルコール

Author (3)： EAMES J (Univ. Chemical Lab., Cambridge, GBR) ,  DE LAS HERAS M A (Univ. Chemical Lab., Cambridge, GBR) ,  WARREN S (Univ. Chemical Lab., Cambridge, GBR)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 37  Issue： 23  Page： 4077-4080  Publication year： Jun. 03, 1996 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： stereospecific reaction ,...
Semi thesaurus term： propanediols ,...

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JST classification (2)： Furans  (CF07072V) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (16)： 4-Hydroxy-5-methyl-5-(phenylthio)-2-hexanone ,  4-Hydroxy-4-[1-(phenylthio)cyclopentyl]-2-butanone ,  4-Hydroxy-4-[[4-(phenylthio)tetrahydro-2H-pyran]-4-yl]-2-butanone ,  4-Hydroxy-4-[[4-(phenylthio)tetrahydro-2H-thiopyran]-4-yl]-2-butanone ,  2,2,5α-Trimethyl-3α-(phenylthio)tetrahydrofuran ,  2,2,5β-Trimethyl-3α-(phenylthio)tetrahydrofuran ,  2β-Methyl-4β-(phenylthio)-1-oxaspiro[4.4]nonane ,  2α-Methyl-4β-(phenylthio)-1-oxaspiro[4.4]nonane ,  2β-Methyl-4β-(phenylthio)-1,8-dioxaspiro[4.5]decane ,  2α-Methyl-4β-(phenylthio)-1,8-dioxaspiro[4.5]decane ,  2β-Methyl-4β-(phenylthio)-1-oxa-8-thiaspiro[4.5]decane ,  2α-Methyl-4β-(phenylthio)-1-oxa-8-thiaspiro[4.5]decane ,  2,5-Dimethyl-5-(phenylthio)-2,4-hexanediol ,  2,2,5,5-Tetramethyl-3-(phenylthio)tetrahydrofuran ,  2α-Methyl-2-phenyl-4β-(phenylthio)-1-oxaspiro[4.4]nonane ,  2β-Methyl-2-phenyl-4β-(phenylthio)-1-oxaspiro[4.4]nonane

Terms in the title (7)： ジオール ,  環化 ,  置換 ,  テトラヒドロフラン ,  立体特異的合成 ,  求核試薬 ,  第三アルコール