Art

J-GLOBAL ID：200902154995916273   Reference number：97A0548252

Construction of 1,3-Oxathiane Ring through Pummerer Reaction of γ,δ-Unsaturated Sulfinyl Compounds.

γ,δ-不飽和スルフィニル化合物のPummerer反応を経由する1,3-オキサチアン環の構築

Author (7)： ABE H (Okayama Univ., Okayama, JPN) ,  FUJII H (Okayama Univ., Okayama, JPN) ,  MASUNARI C (Okayama Univ., Okayama, JPN) ,  ITANI J (Okayama Univ., Okayama, JPN) ,  KASHINO S (Okayama Univ., Okayama, JPN) ,  SHIBAIKE K (Okayama Univ., Okayama, JPN) ,  HARAYAMA T (Okayama Univ., Okayama, JPN)
Material： Chemical and Pharmaceutical Bulletin  (Chemical & Pharmaceutical Bulletin)
Volume： 45  Issue： 5  Page： 778-785  Publication year： May. 1997 
JST Material Number： G0504A  ISSN： 0009-2363  CODEN： CPBTAL  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： polynuclear aromatic compound ,...
Semi thesaurus term： bridged compound ,...

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JST classification (2)： Dioxanes,oxathians,dithians  (CF07099G) ,  Rearrangement reaction,isomerization  (CF02070E)

Substance index (13)： 1-(Ethylsulfinyl)-2-(1-methylethenyl)benzene ,  Ethyl(3-phenyl-3-butenyl) sulfoxide ,  Benzyl(3-ethyl-3-butenyl) sulfoxide ,  (1R,2S,7S)-2α-Nitro-6α-(ethylsulfinyl)tricyclo[5.2.1.0^2,6]dec-8-ene ,  (1R,2S,7S)-2α-Nitro-6α-(propylsulfinyl)tricyclo[5.2.1.0^2,6]dec-8-ene ,  (1R,2S,7S)-2α-Nitro-6α-(benzylsulfinyl)tricyclo[5.2.1.0^2,6]dec-8-ene ,  (1S,4S,5S)-5β-(Ethylsulfinyl)bicyclo[2.2.1]hept-2-ene ,  (1S,4S,5S)-5β-(Benzylsulfinyl)bicyclo[2.2.1]hept-2-ene ,  2,4,4-Trimethyl-4H-3,1-benzoxathiin ,  (1S,3R,5R,7S,9S)-7α-Phenyl-6-oxa-8-thiatricyclo[3.3.1.1^3,9]decane ,  (1R,3R,5R,9S)-2-Nitro-7α-methyl-1β,2β-propano-6-oxa-8-thiatricyclo[3.3.1.1^3,9]decane ,  (1R,3R,5R,9S)-2-Nitro-7α-ethyl-1β,2β-propano-6-oxa-8-thiatricyclo[3.3.1.1^3,9]decane ,  (1R,3R,5R,9S)-2-Nitro-7α-phenyl-1β,2β-propano-6-oxa-8-thiatricyclo[3.3.1.1^3,9]decane

Reference (62)：

• FUJI, K. J. Chem. Soc., Chem. Commun. 1977, 814
• FUJI, K. Tetrahedron Lett. 1981, 22, 2005-2008
• FUJI, K. J. Chem. Soc., Chem. Commun. 1983, 49-50
• FUJI, K. J. Org. Chem. 1985, 50, 657-661
• FUJI, K. J. Org. Chem. 1985, 50, 662-666

Terms in the title (6)： 不飽和 ,  スルフィニル化合物 ,  Pummerer反応 ,  オキサチアン ,  環 ,  構築