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J-GLOBAL ID：200902156774742621   Reference number：02A0351128

Syntheses of Ruthenium(II) Complexes with Pentadentate Ligands and Catalytic Oxidation of Alkane Using 2,6-Dichloropyridine N-Oxide.

四座配位子をもつルテニウム(II)錯体の合成及び2,6-ジクロロピリジンN-オキシドを用いるアルカンの接触酸化

Author (5)： YAMAGUCHI M (Tokyo Metropolitan Univ., Tokyo) ,  ICHII Y (Tokyo Metropolitan Univ., Tokyo) ,  KOSAKA S (Tokyo Metropolitan Univ., Tokyo) ,  MASUI D (Tokyo Metropolitan Univ., Tokyo) ,  YAMAGISHI T (Tokyo Metropolitan Univ., Tokyo)
Material： Chemistry Letters  (Chem Lett)
Issue： 4  Page： 434-435  Publication year： Apr. 05, 2002 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...
Semi thesaurus term： bridged compound

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JST classification (2)： Platinum family element complexes  (CE01100E) ,  Nobel metal catalysts  (CB06122I)

Substance index (12)： Dimethyl sulfoxide ,  Adamantane ,  Chloroform ,  2,6-Dichloropyridine 1-oxide ,  Adamantan-1-ol ,  Adamantane-1,3-diol ,  Adamantan-2-ol ,  1-Chloroadamantane ,  m-Chloroperbenzoic acid ,  Bis(2-pyridylmethyl)di(2-pyridyl)methylamine ,  [Bis(2-pyridylmethyl)amino]malonic acid ,  Decalin-4a-ol

Reference (25)：

• 1) A part of this study has been presented at the 2000 International Chemical Congress of Pacific Basin Societies, Honolulu, 2000, Abstr., INOR 650.
• 2) Abbreviations: N4PY=N,N-bis(2-pyridylmethyl)-N-(bis-2-pyridyl-methyl)amine; N2PY2O=N,N-bis(2-pyridylmethyl)-aminomalonate; TPA=tris(2-pyridylmethyl) amine; MCPBA=m-chloroperbenzoic acid; N-oxide=2,6-dichloropyridine N-oxide.
• 3) a) A. L. Feig and S. J. Lippard, Chem. Rev., 94, 759 (1994).
•  b) B. J. Waller and J. D. Lipscomb, Chem. Rev., 96, 2625 (1996).
•  c) M. Kodera, K. Kano, and T. Funabiki, “Oxygenase and Model Systems,” ed. by T. Funabiki, Kluwer Academic Publishers, Dordrecht (1997), p 283.

Terms in the title (6)： 四座配位子 ,  ルテニウム ,  錯体 ,  N-オキシド ,  アルカン ,  接触酸化