Art

J-GLOBAL ID：200902160852388527   Reference number：00A0468245

Facile construction of the lathyrane-type framework via Cr-Ni-mediated cyclization as a key step.

キー段階としてCr-Ni-媒介環化を経るラチラン型骨格の簡便な構築

Author (3)： MATSUURA T (Keio Univ., Yokohama, JPN) ,  YAMAMURA S (Keio Univ., Yokohama, JPN) ,  TERADA Y (Meijo Univ., Nagoya, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 41  Issue： 13  Page： 2189-2192  Publication year： Mar. 27, 2000 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...
Semi thesaurus term： *bridged compound ,...

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JST classification (2)： Bridged tri-or more-cyclic carbocyclic compounds  (CF06110B) ,  Diterpenes,sesterterpenes  (CF10023R)

Substance index (8)： (7R)-5,11,13,13-Tetramethyl-7β,8β-methano-1,2,3,4,7,8,9,10-octahydrocyclopentacycloundecene-4,10-dione ,  2-[2-(2-Iodo-1-propenyl)-1-cyclopentenyl]-1,3-dioxolane ,  (1S)-2,2-Dimethyl-3α-(1-propynyl)cyclopropane-1α-acetaldehyde ,  Methy 2-oxocyclopentanecarboxylate ,  (+)-3-Carene ,  1-[(1S)-2,2-Dimethyl-3α-(1-propynyl)cyclopropane-1α-yl]-3-methyl-4-[2-(1,3-dioxolane-2-yl)-1-cyclopentenyl]-3-butene-2-ol ,  1-[(1S)-2,2-Dimethyl-3α-(2-iodo-1-propenyl)cyclopropane-1α-yl]-3-methyl-4-(2-formyl-1-cyclopentenyl)-3-butene-2-ol ,  (4R)-5,11,13,13-Tetramethyl-7β,8β-methano-1,2,3,4,7,8,9,10-octahydrocyclopentacycloundecene-4α,10-diol

Terms in the title (8)： キー ,  段階 ,  Cr ,  Ni ,  環化 ,  ラチラン ,  骨格 ,  構築