Art

J-GLOBAL ID：200902163366911837   Reference number：01A0887969

Palladium Catalysis for the Synthesis of Hydrophobic C-6 and C-2 Aryl 2′-Deoxynucleosides. Comparison of C-C versus C-N Bond Formation as well as C-6 versus C-2 Reactivity.

C-6位及びC-2位をアリール基で置換した疎水性の2′-デオキシヌクレオシドを合成するためのパラジウム触媒反応 C-6位とC-2位の反応性並びにC-C結合とC-N結合生成の比較

Author (7)： LAKSHMAN M K (City Coll. CUNY, New York) ,  HILMER J H (City Coll. CUNY, New York) ,  MARTIN J Q (Univ. North Dakota, North Dakota) ,  KEELER J C (Univ. North Dakota, North Dakota) ,  DINH Y Q V (Univ. North Dakota, North Dakota) ,  NGASSA F N (Univ. North Dakota, North Dakota) ,  RUSSON L M (Univ. Oklahoma, Oklahoma)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 123  Issue： 32  Page： 7779-7787  Publication year： Aug. 15, 2001 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *nucleoside analog ,...

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JST classification (1)： Nucleosides,nucleotides  (CF10060K)

Substance index (34)： BINAP ,  2,4-Cyclopentadienyldiphenylphosphine ,  DavePhos ,  CyJohnPhos ,  JohnPhos ,  Tri-tert-butylphosphine ,  3′-O,5′-O-Bis(tert-butyldimethylsilyl)-6-bromo-2′-deoxy-6-deaminoadenosine ,  3′-O,5′-O-Bis(tert-butyldimethylsilyl)-6-phenyl-2′-deoxy-6-deaminoadenosine ,  3′-O,5′-O-Bis(tert-butyldimethylsilyl)-6-(4-methoxyphenyl)-2′-deoxy-6-deaminoadenosine ,  3′-O,5′-O-Bis(tert-butyldimethylsilyl)-6-(3-methoxyphenyl)-2′-deoxy-6-deaminoadenosine ,  3′-O,5′-O-Bis(tert-butyldimethylsilyl)-6-(2-ethoxyphenyl)-2′-deoxy-6-deaminoadenosine ,  3′-O,5′-O-Bis(tert-butyldimethylsilyl)-6-(3-nitrophenyl)-2′-deoxy-6-deaminoadenosine ,  3′-O,5′-O-Bis(tert-butyldimethylsilyl)-6-(4-acetylphenyl)-2′-deoxy-6-deaminoadenosine ,  3′-O,5′-O-Bis(tert-butyldimethylsilyl)-6-(3-thienyl)-2′-deoxy-6-deaminoadenosine ,  Phenylboronic acid ,  4-Methoxyphenylboronic acid ,  3-Methoxyphenylboronic acid ,  2-Ethoxyphenylboronic acid ,  3-Nitrophenylboronic acid ,  4-Acetylphenylboronic acid ,  3-Thienylboronic acid ,  3′-O,5′-O-Bis(tert-butyldimethylsilyl)-6-chloro-2′-deoxy-6-deaminoadenosine ,  2-Bromo-3′-O,5′-O-bis(tert-butyldimethylsilyl)-6-(benzyloxy)-2′-deoxy-6-deaminoadenosine ,  2-Phenyl-3′-O,5′-O-bis(tert-butyldimethylsilyl)-6-(benzyloxy)-2′-deoxy-6-deaminoadenosine ,  2-(4-Methoxyphenyl)-3′-O,5′-O-bis(tert-butyldimethylsilyl)-6-(benzyloxy)-2′-deoxy-6-deaminoadenosine ,  2-(3-Methoxyphenyl)-3′-O,5′-O-bis(tert-butyldimethylsilyl)-6-(benzyloxy)-2′-deoxy-6-deaminoadenosine ,  2-(4-Acetylphenyl)-3′-O,5′-O-bis(tert-butyldimethylsilyl)-6-(benzyloxy)-2′-deoxy-6-deaminoadenosine ,  2-Phenyl-3′-O,5′-O-bis(tert-butyldimethylsilyl)-2′-deoxyinosine ,  2-(4-Methoxyphenyl)-3′-O,5′-O-bis(tert-butyldimethylsilyl)-2′-deoxyinosine ,  2-(3-Methoxyphenyl)-3′-O,5′-O-bis(tert-butyldimethylsilyl)-2′-deoxyinosine ,  2-(4-Acetylphenyl)-3′-O,5′-O-bis(tert-butyldimethylsilyl)-2′-deoxyinosine ,  p-Toluidine ,  N-(4-Methylphenyl)-3′-O,5′-O-bis(tert-butyldimethylsilyl)-2′-deoxyadenosine ,  2-(4-Methylphenylamino)-3′-O,5′-O-bis(tert-butyldimethylsilyl)-6-(benzyloxy)-2′-deoxy-6-deaminoadenosine

Terms in the title (9)： C-6 ,  アリール基 ,  置換 ,  疎水性 ,  パラジウム ,  触媒反応 ,  反応性 ,  C-C結合 ,  C-N結合