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J-GLOBAL ID：200902166432658071   Reference number：98A0156860

Barbier-type Carbonyl-allylation with Allyl Compounds and SnCl₂ in the Presence of PdCl₂[PPh₂(m-C₆H₄SO₃Na)]₂ under Two-phase Conditions.

PdCl₂[PPh₂(m-C₆H₄SO₃Na)]₂存在下,二相条件でのアリル化合物とSnCl₂によるBarbier型カルボニルアリル化

Author (3)： OKANO T (Tottori Univ., Tottori) ,  DOI T (Tottori Univ., Tottori) ,  KIJI J (Tottori Univ., Tottori)
Material： Chemistry Letters  (Chem Lett)
Issue： 1  Page： 5-6  Publication year： Jan. 1998 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...
Semi thesaurus term： allyl alcohol ,...

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JST classification (2)： Aliphatic aldehydes  (CF03180F) ,  Other effects on organic reaction  (CF02120K)

Substance index (23)： Benzaldehyde ,  Sodium 2-formylbenzenesulfonate ,  Allyl chloride ,  (E)-1-Chloro-2-butene ,  Allyl alcohol ,  1-Phenyl-3-buten-1-ol ,  rel-(1S^*,2S^*)-2-Methyl-1-phenyl-3-butene-1-ol ,  rel-(1S^*,2R^*)-2-Methyl-1-phenyl-3-butene-1-ol ,  2-(1-Hydroxy-3-butenyl)benzenesulfonic acid sodium salt ,  Acetaldehyde ,  Isobutyraldehyde ,  3-Phenylpropanal ,  4-Formylbenzoic acid methyl ,  4-Formylbenzonitrile ,  Cyclohexanone ,  3-Pentanone ,  4-Penten-2-ol ,  2-Methyl-5-hexen-3-ol ,  1-Phenyl-5-hexen-3-ol ,  1-(4-Methoxycarbonylphenyl)-3-butene-1-ol ,  α-Allyl-4-cyanobenzenemethanol ,  1-Allylcyclohexanol ,  3-Ethyl-5-hexen-3-ol

Reference (14)：

• 1) Y. Masuyama, S. Mochizuki, and Y. Kurusu, Synth. Commun., 27, 1015 (1997)
•  Y. Masuyama, Adv. Met. -Org. Chem., 3, 255 (1994)
•  Y. Yamamoto and N. Asao, Chem. Rev., 93, 2207 (1993), and references cited therein.
• 2) Y. Masuyama, M. Kishida, and Y. Kurusu, J. Chem. Soc., Chem. Commun., 1995, 1405
•  Y. Masuyama, A. Hayakawa, M. Kishida, and Y. Kurusu, Inorg. Chim. Acta, 220, 155 (1994)

Terms in the title (5)： PdCl2 ,  アリル化合物 ,  SnCl2 ,  カルボニル ,  アリル化