Total Synthesis and Absolute Configuration of Liverwort Diterpenes, (-)-13(15)E,16E-3β-4β-Epoxy-18-hydroxysphenoloba-13(15),16-diene and (-)-13(15)Z,16E-3β,4β-Epoxy-18-hydroxysphenoloba-13(15),16-diene, by Use of the Ring Closing Metathesis Reaction Applied to Seven-Membered Carbocycles with a Trisubstituted Double Bond.

NAKASHIMA K; INOUE K; SONO M; TORI M

Art

J-GLOBAL ID：200902166522844559 Reference number：02A0716602

Total Synthesis and Absolute Configuration of Liverwort Diterpenes, (-)-13(15)E,16E-3β-4β-Epoxy-18-hydroxysphenoloba-13(15),16-diene and (-)-13(15)Z,16E-3β,4β-Epoxy-18-hydroxysphenoloba-13(15),16-diene, by Use of the Ring Closing Metathesis Reaction Applied to Seven-Membered Carbocycles with a Trisubstituted Double Bond.

三置換二重結合を持つ七員炭素環化合物に適用した閉環複分解反応を利用するゼニゴケ類のジテルペン,(-)-13(15)E,16E-3β,4β-エポキシ-18-ヒドロキシスフェノロバ-13(15),16-ジエンおよび(-)-13(15)Z,16E-3β,4β-エポキシ-18-ヒドロキシスフェノロバ-13(15),16-ジエンの全合成と絶対配置

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Author (4)： , , ,
Material：
Volume： 67 Issue： 17 Page： 6034-6040 Publication year： Aug. 23, 2002
JST Material Number： C0328A ISSN： 0022-3263 CODEN： JOCEAH Document type： Article
Article type：原著論文 Country of issue： United States (USA) Language： ENGLISH (EN)

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Configuration and conformation of molecules , Diterpenes,sesterterpenes

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