Art

J-GLOBAL ID：200902167621520028   Reference number：02A0676518

Mechanistic studies on the hydrosilylation of an acetylene cobalt complex; trapping an active catalyst Co₂(CO)₆ causing olefin-isomerization and O-silylation.

アセチレンコバルト錯体類のヒドロシリル化に関する機構研究 オレフィン-異性化及びO-シリル化を引き起こす活性な触媒Co₂(CO)₆の捕捉

Author (6)： KITA K (Nagoya Univ., Nagoya, JPN) ,  TANDA H (Nagoya Univ., Nagoya, JPN) ,  HAMAJIMA A (Nagoya Univ., Nagoya, JPN) ,  BABA T (Nagoya Univ., Nagoya, JPN) ,  TAKAI S (Nagoya Univ., Nagoya, JPN) ,  ISOBE M (Nagoya Univ., Nagoya, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 58  Issue： 32  Page： 6485-6492  Publication year： Aug. 05, 2002 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *cobalt complex ,...
Semi thesaurus term： ciguatoxin

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JST classification (3)： Seven-membered heterocyclic compounds  (CF07110I) ,  Cobalt bnd nickel complexes  (CE01092Y) ,  Rearrangement reaction,isomerization  (CF02070E)

Substance index (18)： Propargyl alcohol ,  (4S,5S,6R,7R,8R,10S,11R,15R)-5,6-Bis(benzyloxy)-4,8:7,11:10,15-triepoxy-1-heptadecene-13-yne-17-ol ,  Triethylsilane ,  (4S,5S,6R,7R,8R,10S,11R,15R)-5,6-Bis(benzyloxy)-13-(triethylsilyl)-4,8:7,11:10,15-triepoxy-1,13-heptadecadiene-17-ol ,  (4S,5S,6R,7R,8R,10S,11R,15R)-4,8:7,11:10,15-Triepoxy-5,6-bis(benzyloxy)-17-(triethylsilyloxy)heptadeca-1,13-diene ,  (4S,5S,6R,7R,8R,10S,11R,15R)-5,6-Bis(benzyloxy)-13-(triethylsilyl)-4,8:7,11:10,15-triepoxy-2,13-heptadecadiene-17-ol ,  (4S,5S,6R,7R,8R,12R)-4,8:7,12-Diepoxy-5,6-bis(benzyloxy)-14-phenyl-1-tetradecene-10-yne ,  (4S,5S,6R,7R,8R,12R)-4,8:7,12-Diepoxy-5,6-bis(benzyloxy)-10-(triethylsilyl)-14-phenyl-1,10-tetradecadiene ,  (4S,5S,6R,7R,8R,12R)-4,8:7,12-Diepoxy-5,6-bis(benzyloxy)-10-(triethylsilyl)-14-phenyl-2,10-tetradecadiene ,  (3R,7R,8R,9R,10S,11S)-1-Phenyl-3,8:7,11-diepoxy-9,10-bis(benzyloxy)-5-(triethylsilyl)-4-tetradecene ,  2-Methyl-3-butyn-2-ol ,  Bis(trimethylsilyl)acetylene ,  2-(Triethylsilyl)-2-propene-1-ol ,  (E)-3-(Triethylsilyl)-2-propen-1-ol ,  10-(Tetrahydro-2H-pyran-2-yl)-1-decene ,  10-(Tetrahydro-2H-pyran-2-yl)-2,4,6-decatriene ,  3,7-Dimethyl-2,6-octene-1-ol ,  1-(Triethylsiloxy)-3,7-dimethyl-2,6-octene

Terms in the title (12)： アセチレン ,  コバルト錯体 ,  ヒドロシリル化 ,  研究 ,  オレフィン ,  異性化 ,  シリル化 ,  活性 ,  触媒 ,  CO2 ,  CO ,  捕捉