Art

J-GLOBAL ID：200902168757788233   Reference number：99A0528278

The Asymmetric Addition of Trimethylsilyl Cyanide to Aldehydes Catalyzed by Chiral (Salen) Titanium Complexes.

キラルな(Salen)チタン錯体を触媒とするトリメチルシリルシアニドのアルデヒドへの不斉付加

Author (9)： BELOKON Y N (A.N. Nesmeyanov Inst. Organoelement Compounds, Russian Acad. Sci., Moscow, RUS) ,  CAVEDA-CEPAS S (Univ. Wales, Gwynedd, GBR) ,  GREEN B (Univ. Wales, Gwynedd, GBR) ,  IKONNIKOV N S (A.N. Nesmeyanov Inst. Organoelement Compounds, Russian Acad. Sci., Moscow, RUS) ,  KHRUSTALEV V N (A.N. Nesmeyanov Inst. Organoelement Compounds, Russian Acad. Sci., Moscow, RUS) ,  LARICHEV V S (A.N. Nesmeyanov Inst. Organoelement Compounds, Russian Acad. Sci., Moscow, RUS) ,  MOSCALENKO M A (A.N. Nesmeyanov Inst. Organoelement Compounds, Russian Acad. Sci., Moscow, RUS) ,  NORTH M (Univ. Wales, Gwynedd, GBR) ,  YASHKINA L V (A.N. Nesmeyanov Inst. Organoelement Compounds, Russian Acad. Sci., Moscow, RUS)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 121  Issue： 16  Page： 3968-3973  Publication year： Apr. 28, 1999 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： azomethine ,...

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JST classification (3)： Aromatic monocyclic aldehydes  (CF05160X) ,  Organosilicon compounds  (CF08030C) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (36)： (1R,2R)-1,2-Bis(salicylideneamino)cyclohexane ,  N,N′-Bis(3-tert-butylsalicylidene)cyclohexane-1β,2α-diamine ,  N,N′-Bis(3-tert-butyl-5-methylsalicylidene)cyclohexane-1β,2α-diamine ,  N,N′-Bis(3-tert-butyl-5-methoxysalicylidene)cyclohexane-1β,2α-diamine ,  N,N′-Bis(3,5-ditert-butylsalicylidene)cyclohexane-1β,2α-diamine ,  2,2′-[(Cyclohexane-1β,2α-diyl)bisnitrilomethylidyne]bis(4-trityl-6-tert-butylphenol) ,  2,2′-[(Cyclohexane-1β,2α-diyl)bisnitrilomethylidyne]bis(4-nitro-6-tert-butylphenol) ,  Trimethylsilyl cyanide ,  (S)-Phenyl(trimethylsiloxy)acetonitrile ,  (S)-α-(Trimethylsiloxy)-2-methylbenzeneacetonitrile ,  (S)-α-(Trimethylsiloxy)-3-methylbenzeneacetonitrile ,  (S)-α-(Trimethylsiloxy)-4-methylbenzeneacetonitrile ,  (S)-α-(Trimethylsiloxy)-2-methoxybenzeneacetonitrile ,  (S)-α-(Trimethylsiloxy)-3-methoxybenzeneacetonitrile ,  (S)-α-(Trimethylsiloxy)-4-methoxybenzeneacetonitrile ,  Benzaldehyde ,  2-Methylbenzaldehyde ,  3-Methylbenzaldehyde ,  4-Methylbenzaldehyde ,  2-Methoxybenzaldehyde ,  3-Methoxybenzaldehyde ,  4-Methoxybenzaldehyde ,  2,4-Dimethoxybenzaldehyde ,  3,4-Dimethoxybenzaldehyde ,  3,5-Dimethoxybenzaldehyde ,  4-(Trifluoromethyl)benzaldehyde ,  4-Nitrobenzaldehyde ,  Pivalaldehyde ,  Propionaldehyde ,  (αS)-α-(Trimethylsiloxy)-2,4-dimethoxybenzeneacetonitrile ,  (αS)-α-(Trimethylsiloxy)-3,4-dimethoxybenzeneacetonitrile ,  (S)-α-(Trimethylsiloxy)-3,5-dimethoxybenzeneacetonitrile ,  (S)-α-(Trimethylsiloxy)-4-(trifluoromethyl)benzeneacetonitrile ,  (S)-α-(Trimethylsiloxy)-4-nitrobenzeneacetonitrile ,  (S)-2-(Trimethylsiloxy)-3,3-dimethylbutanenitrile ,  (S)-2-(Trimethylsiloxy)butanenitrile

Terms in the title (5)： キラル ,  チタン錯体 ,  触媒 ,  トリメチルシリルシアニド ,  アルデヒド