Art

J-GLOBAL ID：200902169030881539   Reference number：98A0313845

Rhodium-Catalyzed Insertion of Carbenoids into β C-H Bonds of Silacycloalkanes: A Facile and General Approach to Functionalized Silacycloalkanes.

シラシクロアルカンのβC-H結合へのカルベノイドのロジウム触媒挿入 官能化シラシクロアルカンへの容易で一般的な経路

Author (5)： HATANAKA Y (National Inst. Materials and Chemical Res., Ibaraki, JPN) ,  WATANABE M (Sci. Univ. Tokyo, Chiba, JPN) ,  ONOZAWA S (National Inst. Materials and Chemical Res., Ibaraki, JPN) ,  TANAKA M (National Inst. Materials and Chemical Res., Ibaraki, JPN) ,  SAKURAI H (Sci. Univ. Tokyo, Chiba, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 63  Issue： 3  Page： 422-423  Publication year： Feb. 06, 1998 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *silicon heterocyclic compound ,...
Semi thesaurus term： acetic acids

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JST classification (1)： Organosilicon compounds  (CF08030C)

Substance index (11)： 1,1-Dimethylsilacyclobutane ,  1,1-Dimethyl-1-silacyclopentane ,  1,1-Dimethylsilacyclohexane ,  2,6-Dimethyl-2,6-disilaheptane ,  1-(Dimethylsilyl)-3-(methylphenylsilyl)propane ,  1,1-Dimethylsilacyclobutane-3-acetic acid tert-butyl ester ,  1,1-Dimethylsilacyclobutane-3-acetic acid ethyl ester ,  1,1-Dimethylsilacyclopentane-3-acetic acid tert-butyl ester ,  1,1-Dimethylsilacyclohexane-3-acetic acid tert-butyl ester ,  3-[(Dimethylsilyl)methyl]-4-(dimethylsilyl)butanoic acid ethyl ester ,  3-[(Dimethylsilyl)methyl]-4-(methylphenylsilyl)butanoic acid ethyl ester

Terms in the title (6)： C-H結合 ,  カルベノイド ,  ロジウム触媒 ,  官能化 ,  容易 ,  経路