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J-GLOBAL ID：200902169842801890   Reference number：02A0165492

Absolute Structure of Panaxytriol.

パナキシトリオールの絶対構造

Author (6)： SATOH M (Showa Coll. Pharmaceutical Sci., Tokyo, JPN) ,  ISHII M (Showa Coll. Pharmaceutical Sci., Tokyo, JPN) ,  WATANABE M (Showa Coll. Pharmaceutical Sci., Tokyo, JPN) ,  ISOBE K (Showa Coll. Pharmaceutical Sci., Tokyo, JPN) ,  UCHIYAMA T (Nihon Univ., Chiba, JPN) ,  FUJIMOTO Y (Nihon Univ., Chiba, JPN)
Material： Chemical and Pharmaceutical Bulletin  (Chemical & Pharmaceutical Bulletin)
Volume： 50  Issue： 1  Page： 126-128  Publication year： Jan. 01, 2002 
JST Material Number： G0504A  ISSN： 0009-2363  CODEN： CPBTAL  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *acetylenic compound ,...

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JST classification (1)： Aliphatic alcohols  (CF03090H)

Substance index (25)： Panaxytriol ,  rac-(3R^*)-1-Heptene-4,6-diyne-3-ol ,  Acetic acid (R)-1-vinyl-2,4-pentadiyne-1-yl ester ,  (S)-1-Heptene-4,6-diyne-3-ol ,  (R)-1-Heptene-4,6-diyne-3-ol ,  R-MTPA-Cl ,  (S)-α-Methoxy-α-(trifluoromethyl)benzeneacetic acid (R)-1-vinyl-2,4-pentadiyne-1-yl ester ,  (S)-α-Methoxy-α-(trifluoromethyl)benzeneacetic acid (S)-1-vinyl-2,4-pentadiyne-1-yl ester ,  rac-(3R^*)-8-[(4R)-2,2-Dimethyl-5β-heptyl-1,3-dioxolane-4α-yl]-1-octene-4,6-diyne-3-ol ,  rac-(3R^*)-8-[(4S)-2,2-Dimethyl-5α-heptyl-1,3-dioxolane-4β-yl]-1-octene-4,6-diyne-3-ol ,  (3R,9R,10R)-Panaxytriolacetate ,  (3S)-8-[(4R)-2,2-Dimethyl-5β-heptyl-1,3-dioxolane-4α-yl]-1-octene-4,6-diyne-3-ol ,  (3R,9S,10S)-Panaxytriolacetate ,  (3S)-8-[(4S)-2,2-Dimethyl-5α-heptyl-1,3-dioxolane-4β-yl]-1-octene-4,6-diyne-3-ol ,  (3R)-8-[(4R)-2,2-Dimethyl-5β-heptyl-1,3-dioxolane-4α-yl]-1-octene-4,6-diyne-3-ol ,  (3R)-8-[(4S)-2,2-Dimethyl-5α-heptyl-1,3-dioxolane-4β-yl]-1-octene-4,6-diyne-3-ol ,  (R)-α-Methoxy-α-(trifluoromethyl)benzeneacetic acid (R)-1-vinyl-6-[(4R)-2,2-dimethyl-5β-heptyl-1,3-dioxolane-4α-yl]-2,4-hexadiyne-1-yl ester ,  (S)-α-Methoxy-α-(trifluoromethyl)benzeneacetic acid (R)-1-vinyl-6-[(4R)-2,2-dimethyl-5β-heptyl-1,3-dioxolane-4α-yl]-2,4-hexadiyne-1-yl ester ,  (R)-α-Methoxy-α-(trifluoromethyl)benzeneacetic acid (R)-1-vinyl-6-[(4S)-2,2-dimethyl-5α-heptyl-1,3-dioxolane-4β-yl]-2,4-hexadiyne-1-yl ester ,  (S)-α-Methoxy-α-(trifluoromethyl)benzeneacetic acid (R)-1-vinyl-6-[(4S)-2,2-dimethyl-5α-heptyl-1,3-dioxolane-4β-yl]-2,4-hexadiyne-1-yl ester ,  (R)-α-Methoxy-α-(trifluoromethyl)benzeneacetic acid (S)-1-vinyl-6-[(4R)-2,2-dimethyl-5β-heptyl-1,3-dioxolane-4α-yl]-2,4-hexadiyne-1-yl ester ,  (S)-α-Methoxy-α-(trifluoromethyl)benzeneacetic acid (S)-1-vinyl-6-[(4R)-2,2-dimethyl-5β-heptyl-1,3-dioxolane-4α-yl]-2,4-hexadiyne-1-yl ester ,  (R)-α-Methoxy-α-(trifluoromethyl)benzeneacetic acid (S)-1-vinyl-6-[(4S)-2,2-dimethyl-5α-heptyl-1,3-dioxolane-4β-yl]-2,4-hexadiyne-1-yl ester ,  (S)-α-Methoxy-α-(trifluoromethyl)benzeneacetic acid (S)-1-vinyl-6-[(4S)-2,2-dimethyl-5α-heptyl-1,3-dioxolane-4β-yl]-2,4-hexadiyne-1-yl ester ,  Panaxytriol

Reference (9)：

• 1) Satoh M., Takeuchi N., Fujimoto Y., Chem. Pharm. Bull., 45, 1114—1116 (1997).
• 2) Kobayashi M., Mahmund T., Umezome T., Wang W., Murakami N., Tetrahedron, 53, 15691—15700 (1997).
• 3) Lu W., Zheng G., Gao D., Cai J., Tetrahedron, 55, 7157—7168 (1999).
• 4) Gurjar M. K., Kumar V. S., Rao B. V., Tetrahedron, 55, 12563—12576 (1999).
• 5) Naoshima Y., Kamezawa M., Kimura T., Okimoto F., Watanabe M., Tachibana H., Ohtani T., <i>Recent Res. Devel. Org. & Bioorg. Chem.</i>, <b>4</b>, 1—16 (2001).

Terms in the title (1)： パナキシトリオール