Art

J-GLOBAL ID：200902173313823206   Reference number：02A0655263

Stereoselective Synthesis of Both syn- and anti-N-tert-Alkylamines Using Highly Stereospecific Crotylation of Ketone-Derived Acylhydrazones with Crotyltrichlorosilanes.

ケトンから誘導されたアシルヒドラゾンのクロチルトリクロロシランによる高度に立体特異的なクロチル化を利用したN-t-アルキルアミンのsyn-およびanti-両異性体の立体選択的合成

Author (3)： OGAWA C (Univ. Tokyo, Tokyo, JPN) ,  SUGIURA M (Univ. Tokyo, Tokyo, JPN) ,  KOBAYASHI S (Univ. Tokyo, Tokyo, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 67  Issue： 15  Page： 5359-5364  Publication year： Jul. 26, 2002 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *hydrazone ,...

   To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=02A0655263&from=J-GLOBAL&jstjournalNo=C0328A") }}

JST classification (1)： Nitrogen derivatives of aromatic monocyclic carboxylic acids  (CF05200S)

Substance index (41)： Acetophenone N-benzoyl hydrazone ,  Propiophenone benzoylhydrazone ,  Butyrophenone benzoylhydrazone ,  Valerophenone benzoylhydrazone ,  1-(2-Naphthyl)ethanone benzoylhydrazone ,  3′-Nitroacetophenone benzoylhydrazone ,  4′-Bromoacetophenone benzoylhydrazone ,  4′-Chloropropiophenone benzoylhydrazone ,  4′-Chlorobutyrophenone benzoylhydrazone ,  4′-Methylpropiophenone benzoylhydrazone ,  4′-Methylbutyrophenone benzoylhydrazone ,  4′-Ethylpropiophenone benzoylhydrazone ,  ((Z)-2-Butenyl)trichlorosilane ,  ((E)-2-Butenyl)trichlorosilane ,  rel-N′-[(1S^*,2S^*)-1,2-Dimethyl-1-phenyl-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1,2-Dimethyl-1-phenyl-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2S^*)-1-Ethyl-2-methyl-1-phenyl-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1-Ethyl-2-methyl-1-phenyl-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2S^*)-1-Propyl-2-methyl-1-phenyl-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1-Propyl-2-methyl-1-phenyl-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2S^*)-1-Butyl-2-methyl-1-phenyl-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1-Butyl-2-methyl-1-phenyl-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2S^*)-1,2-Dimethyl-1-(2-naphthyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1,2-Dimethyl-1-(2-naphthyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2S^*)-1,2-Dimethyl-1-(3-nitrophenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1,2-Dimethyl-1-(3-nitrophenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2S^*)-1,2-Dimethyl-1-(4-bromophenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1,2-Dimethyl-1-(4-bromophenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2S^*)-1-Ethyl-2-methyl-1-(4-chlorophenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1-Ethyl-2-methyl-1-(4-chlorophenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2S^*)-1-Propyl-2-methyl-1-(4-chlorophenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1-Propyl-2-methyl-1-(4-chlorophenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2S^*)-1-Ethyl-2-methyl-1-(4-methylphenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1-Ethyl-2-methyl-1-(4-methylphenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2S^*)-1-Propyl-2-methyl-1-(4-methylphenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1-Propyl-2-methyl-1-(4-methylphenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2S^*)-1-Ethyl-2-methyl-1-(4-ethylphenyl)-3-butenyl]benzhydrazide ,  rel-N′-[(1S^*,2R^*)-1-Ethyl-2-methyl-1-(4-ethylphenyl)-3-butenyl]benzhydrazide ,  rel-N-[(1S^*,2S^*)-1,2-Dimethyl-1-phenyl-3-butenyl]p-toluenesulfonamide ,  rel-(3S^*,4S^*)-3-Methyl-4-phenyl-1-heptene-4-amine ,  rel-(3R^*,4S^*)-3-Methyl-4-phenyl-1-heptene-4-amine

Terms in the title (7)： ケトン ,  誘導 ,  クロチルトリクロロシラン ,  チル ,  アルキルアミン ,  異性体 ,  立体選択的合成