Art

J-GLOBAL ID：200902175441556884   Reference number：00A0919561

An Intramolecular Anionic Migration of a Stannyl Group from the 6-Position of 1-(2-Deoxy-D-erythro-pent-1-enofuranosyl)uracil to the 2′-Position: Synthesis of 2′-Substituted 1′,2′-Unsaturated Uridines.

1-(2-デオキシ-D-erythro-ペンタ-1-エノフラノシル)ウラシルの6位から2′位へのスタンニル基の分子内アニオン移動 2′-置換1′,2′-不飽和ウリジン類の合成

Author (9)： KUMAMOTO H (Showa Univ., Tokyo, JPN) ,  SHINDOH S (Showa Univ., Tokyo, JPN) ,  TANAKA H (Showa Univ., Tokyo, JPN) ,  ITOH Y (Showa Univ., Tokyo, JPN) ,  HARAGUCHI K (Showa Univ., Tokyo, JPN) ,  KITTAKA A (Showa Univ., Tokyo, JPN) ,  MIYASAKA T (Showa Univ., Tokyo, JPN) ,  KONDO M (Showa Univ., Tokyo, JPN) ,  NAKAMURA K T (Showa Univ., Tokyo, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 56  Issue： 30  Page： 5363-5371  Publication year： Jul. 21, 2000 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： lithiation ,...
Semi thesaurus term： anion transport

   To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=00A0919561&from=J-GLOBAL&jstjournalNo=E0234A") }}

JST classification (2)： Nucleosides,nucleotides  (CF10060K) ,  Rearrangement reaction,isomerization  (CF02070E)

Substance index (29)： 3′-O,5′-O-Di(tert-butyldimethylsilyl)-1′,2′-didehydro-2′-deoxyuridine ,  2′-(Tributylstannyl)-3′-O,5′-O-bis(tert-butyldimethylsilyl)-2′-deoxy-1′,2′-didehydrouridine ,  1-[4α-(tert-Butyldimethylsilyloxy)-5β-[(tert-butyldimethylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]-6-(tributylstannyl)uracil ,  1-[(4R,5R)-3-(Tributylstannyl)-4-(tert-butyldimethylsilyloxy)-5-[(tert-butyldimethylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]-6-(tributylstannyl)pyrimidine-2,4(1H,3H)-dione ,  1-[(4R,5R)-3-(Trimethylsilyl)-4-(tert-butyldimethylsilyloxy)-5-[(tert-butyldimethylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]-6-(trimethylsilyl)pyrimidine-2,4(1H,3H)-dione ,  Tributylchlorostannane ,  Tributylchlorosilane ,  1-[(4S,5R)-4-(tert-Butyldimethylsilyloxy)-5-[(tert-butyldimethylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]-6-methylpyrimidine-2,4(1H,3H)-dione ,  1-[(4S,5R)-4-(tert-Butyldimethylsilyloxy)-5-[(tert-butyldimethylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]-6-phenylpyrimidine-2,4(1H,3H)-dione ,  1-[(4S,5R)-4-(tert-Butyldiphenylsilyloxy)-5-[(tert-butyldiphenylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]-6-(trimethylsilyl)pyrimidine-2,4(1H,3H)-dione ,  1-[(4R,5R)-3-(Trimethylsilyl)-4-(tert-butyldiphenylsilyloxy)-5-[(tert-butyldiphenylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]pyrimidine-2,4(1H,3H)-dione ,  1-[(4S,5R)-4-(tert-Butyldiphenylsilyloxy)-5-[(tert-butyldiphenylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]pyrimidine-2,4(1H,3H)-dione ,  1-[(4R,5R)-3-Iodo-4-(tert-butyldiphenylsilyloxy)-5-[(tert-butyldiphenylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]pyrimidine-2,4(1H,3H)-dione ,  1-[(4R,5R)-3-Bromo-4-(tert-butyldiphenylsilyloxy)-5-[(tert-butyldiphenylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]pyrimidine-2,4(1H,3H)-dione ,  1-[(4R,5R)-3-Chloro-4-(tert-butyldiphenylsilyloxy)-5-[(tert-butyldiphenylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]pyrimidine-2,4(1H,3H)-dione ,  1-[(4R,5R)-3-Fluoro-4-(tert-butyldiphenylsilyloxy)-5-[(tert-butyldiphenylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]pyrimidine-2,4(1H,3H)-dione ,  1-[(4S,5R)-3-Phenyl-4-(tert-butyldiphenylsilyloxy)-5-[(tert-butyldiphenylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]pyrimidine-2,4(1H,3H)-dione ,  1-[(4S,5R)-3-Benzyl-4-(tert-butyldiphenylsilyloxy)-5-[(tert-butyldiphenylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]pyrimidine-2,4(1H,3H)-dione ,  1-[(4S,5R)-3-Vinyl-4-(tert-butyldiphenylsilyloxy)-5-[(tert-butyldiphenylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]pyrimidine-2,4(1H,3H)-dione ,  1-[(4S,5R)-3-Methyl-4-(tert-butyldiphenylsilyloxy)-5-[(tert-butyldiphenylsilyloxy)methyl]-4,5-dihydrofuran-2-yl]pyrimidine-2,4(1H,3H)-dione ,  2′-Iodo-2′-deoxy-1′,2′-didehydrouridine ,  2′-Bromo-2′-deoxy-1′,2′-didehydrouridine ,  2′-Chloro-2′-deoxy-1′,2′-didehydrouridine ,  2′-Phenyl-2′-deoxy-1′,2′-didehydrouridine ,  2′-Benzyl-2′-deoxy-1′,2′-didehydrouridine ,  2′-Vinyl-2′-deoxy-1′,2′-didehydrouridine ,  2′-Methyl-2′-deoxy-1′,2′-didehydrouridine ,  1-[(4S,5R)-4-Hydroxy-5-(hydroxymethyl)-4,5-dihydrofuran-2-yl]-6-methylpyrimidine-2,4(1H,3H)-dione ,  1-[5-(Hydroxymethyl)-2-furyl]pyrimidine-2,4(1H,3H)-dione

Terms in the title (6)： ペンタ ,  ウラシル ,  アニオン ,  置換 ,  不飽和 ,  ウリジン