Art

J-GLOBAL ID：200902179545573840   Reference number：01A0697219

Novel and efficient transformation of α-amino nitrile to α-imino and α-amide nitriles in asymmetric Strecker synthesis.

不斉Strecker合成におけるα-アミノニトリルのα-イミノ及びα-アミドニトリルへの新規で効率のよい変換

Author (7)： NAMBA K (Osaka City Univ., Osaka, JPN) ,  KAWASAKI M (Osaka City Univ., Osaka, JPN) ,  TAKADA I (Osaka City Univ., Osaka, JPN) ,  IWAMA S (Osaka City Univ., Osaka, JPN) ,  IZUMIDA M (Osaka City Univ., Osaka, JPN) ,  SHINADA T (Osaka City Univ., Osaka, JPN) ,  OHFUNE Y (Osaka City Univ., Osaka, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 42  Issue： 22  Page： 3733-3736  Publication year： May. 28, 2001 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *amino acid ,...

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JST classification (1)： Oxazines  (CF07100X)

Substance index (32)： (5S,8aα)-3,3,7-Trimethyl-4-oxo-5α-benzylhexahydro-1H,3H-2-oxa-3a,6-diazaazulene-7β-carbonitrile ,  (7R)-3,3,7-Trimethyl-4-oxo-5-benzyl-4,7,8,8aα-tetrahydro-1H,3H-2-oxa-3a,6-diazaazulene-7β-carbonitrile ,  (2R,4S)-2,4-Diamino-2-methyl-5-hydroxyvaleric acid ,  Manzacidin A ,  (3S)-3-Methyl-5β-isopropyl-6-oxomorpholine-3α-carbonitrile ,  (3S)-3-Methyl-5-isopropyl-6-oxo-3,6-dihydro-2H-1,4-oxazine-3α-carbonitrile ,  (2S)-2-(Isobutyrylamino)-2-methyl-3-hydroxypropiononitrile ,  2-Methyl-D-serine ,  (2S)-2β-Isopropyl-3-(pivaloyloxymethyl)-5β-benzyl-6-oxomorpholine-3α-carbonitrile ,  (2S)-2β-Isopropyl-3-(pivaloyloxymethyl)-5-benzyl-6-oxo-3,6-dihydro-2H-1,4-oxazine-3α-carbonitrile ,  (2R)-2-(Pivaloyloxymethyl)-2-(phenylacetylamino)-3-hydroxy-4-methylpentanenitrile ,  (2R,3S)-2-Amino-2-(hydroxymethyl)-3-hydroxy-4-methylvaleric acid ,  (3R,7aα)-2-Oxo-3β-benzyloctahydrocyclopenta[b]-1,4-oxazine-4aα-carbonitrile ,  (4aR,7aα)-2-Oxo-3-benzyl-2,4a,5,6,7,7aα-hexahydrocyclopenta[b]-1,4-oxazine-4aα-carbonitrile ,  (1R)-1-(Phenylacetylamino)-2α-hydroxycyclopentane-1β-carbonitrile ,  (1S,2R)-1-Amino-2-hydroxycyclopentanecarboxylic acid ,  (3S,8aβ)-2-Oxo-3α-benzyloctahydro-2H-1,4-benzoxazine-4aβ-carbonitrile ,  (3S,8aα)-2-Oxo-3α-benzyloctahydro-2H-1,4-benzoxazine-4aβ-carbonitrile ,  (4aS)-2-Oxo-3-benzyl-4a,5,6,7,8,8aβ-hexahydro-2H-1,4-benzoxazine-4aβ-carbonitrile ,  (4aS)-2-Oxo-3-benzyl-4a,5,6,7,8,8aα-hexahydro-2H-1,4-benzoxazine-4aβ-carbonitrile ,  (1S)-1-(Phenylacetylamino)-2β-hydroxycyclohexane-1α-carbonitrile ,  (1S)-1-(Phenylacetylamino)-2α-hydroxycyclohexane-1α-carbonitrile ,  (1R,2S)-1-Amino-2-hydroxycyclohexanecarboxylic acid ,  (1R,2R)-1-Amino-2-hydroxycyclohexanecarboxylic acid ,  (3S,8aα)-2-Oxo-3α-tert-butyloctahydro-2H-1,4-benzoxazine-4aβ-carbonitrile ,  (4aS)-2-Oxo-3-tert-butyl-4a,5,6,7,8,8aα-hexahydro-2H-1,4-benzoxazine-4aβ-carbonitrile ,  (1S)-1-(Pivaloylacetylamino)-2α-hydroxycyclohexane-1α-carbonitrile ,  (3aα,7aα,8aα)-2,6-Dioxo-5β-benzyldecahydro-7-oxa-4-aza-1H-cyclopenta[a]indene-3bα-carbonitrile ,  (3aR)-2,6-Dioxo-5-benzyl-2,3,3aα,3b,6,7aα,8,8aα-octahydro-7-oxa-4-aza-1H-cyclopenta[a]indene-3bα-carbonitrile ,  (1R,3aα,6aα)-1-Amino-2β-hydroxy-5-oxooctahydropentalene-1α-carboxylic acid ,  (3S,7S,8aβ)-2-Oxo-2′,2′-dimethyl-3α-benzyl-5β-[2-(tert-butyldimethylsiloxy)ethyl]octahydrospiro[7H-1,4-benzoxazine-7,4′-[1,3]dioxolane]-4aβ-carbonitrile ,  (4aS,7S)-2-Oxo-2′,2′-dimethyl-3-benzyl-5β-[2-(tert-butyldimethylsiloxy)ethyl]-2,4a,5,6,8,8aβ-hexahydrospiro[7H-1,4-benzoxazine-7,4′-[1,3]dioxolane]-4aβ-carbonitrile

Terms in the title (2)： Strecker合成 ,  アミノニトリル