Art

J-GLOBAL ID：200902180766365167   Reference number：99A0020004

Novel Cage Polycarbosilanes. Preparation and Characterization of Dodecamethyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octane and Its Derivatives.

新規かご状ポリカルボシラン ドデカメチル-2,3,5,6,7,8-ヘキサシラビシクロ[2.2.2]オクタン及びその誘導体の合成及びキャラクタリゼーション

Author (4)： SHIMIZU M (Kyoto Univ., Kyoto) ,  INAMASU N (Tokyo Inst. Technol., Kanagawa) ,  NISHIHARA Y (Tokyo Inst. Technol., Kanagawa) ,  HIYAMA T (Kyoto Univ., Kyoto)
Material： Chemistry Letters  (Chem Lett)
Issue： 11  Page： 1145-1146  Publication year： Nov. 1998 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...
Semi thesaurus term： bridged compound

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JST classification (1)： Organosilicon compounds  (CF08030C)

Substance index (11)： 2,2,3,3,5,5,6,6,7,7,8,8-Dodecamethyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octane ,  1-(Trimethylsilyl)-2,2,3,3,5,5,6,6,7,7,8,8-dodecamethyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octane ,  1-(Phenyldimethylsilyl)-2,2,3,3,5,5,6,6,7,7,8,8-dodecamethyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octane ,  1-(Tributylstannyl)-2,2,3,3,5,5,6,6,7,7,8,8-dodecamethyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octane ,  1,2,2,3,3,5,5,6,6,7,7,8,8-Tridecamethyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octane ,  1-Allyl-2,2,3,3,5,5,6,6,7,7,8,8-dodecamethyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octane ,  1,4-Bis(trimethylsilyl)-2,2,3,3,5,5,6,6,7,7,8,8-dodecamethyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octane ,  1-(Trimethylsilyl)-2,2,3,3,4,5,5,6,6,7,7,8,8-tridecamethyl-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octane ,  Bis(phenylthio)methane ,  1,1,2,2-Tetramethyl-1,2-bis[bis(phenylthio)methyl]disilane ,  1,1,2,2,4,4,5,5-Octamethyl-3,6-bis(phenylthio)-1,2,4,5-tetrasilacyclohexane

Reference (26)：

• 1) a) M. Kumada and K. Tamao, Adv. Organomet. Chem., 6, 19 (1968).
•  b) H. Sakurai, J. Organomet. Chem., 200, 261 (1980).
•  c) R. West, in “Comprehensive Organometallic Chemistry,” ed by G. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon Press, Oxford (1982), Vol. 2, p. 365.
•  d) R. D. Miller and J. Michl, Chem. Rev., 89, 1359 (1989).
•  e) R. West, in “Comprehensive Organometallic Chemistry II,” ed by E. W. Abel, F. G. A. Stone, and G. Wilkinson, Pergamon, Oxford (1995), Vol. 2, p. 77.

Terms in the title (5)： かご ,  ポリカルボシラン ,  オクタン ,  誘導体 ,  キャラクタリゼーション