Art

J-GLOBAL ID：200902183024855057   Reference number：97A0103025

Kinetic Resolution of Racemic 2-Substituted 3-Cyclopenten-1-ols by Lipase-Catalyzed Transesterifications: A Rational Strategy To Improve Enantioselectivity.

リパーゼ接触エステル交換による2-置換3-シクロペンテン-1-オールラセミ体の速度論的分割 エナンチオ選択性を改良するための合理的戦略

Author (5)： EMA T (Okayama Univ., Okayama, JPN) ,  MAENO S (Okayama Univ., Okayama, JPN) ,  TAKAYA Y (Okayama Univ., Okayama, JPN) ,  SAKAI T (Okayama Univ., Okayama, JPN) ,  UTAKA M (Okayama Univ., Okayama, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 61  Issue： 24  Page： 8610-8616  Publication year： Nov. 29, 1996 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： alicyclic alcohol ,...
Semi thesaurus term： acetamides ,...

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JST classification (2)： Cyclopentanes  (CF04040L) ,  Other separation methods  (CC01060D)

Substance index (11)： 2-[(Dimethylcarbamoyl)methyl]-3-cyclopenten-1-ol ,  2-[2-(tert-Butyldimethylsiloxy)ethyl]-3-cyclopenten-1-ol ,  Acetic acid [(1R,2S)-2-[(dimethylcarbamoyl)methyl]-3-cyclopenten-1-yl] ester ,  Propanoic acid [(1R,2S)-2-[(dimethylcarbamoyl)methyl]-3-cyclopenten-1-yl] ester ,  Butyric acid [(1R,2S)-2-[(dimethylcarbamoyl)methyl]-3-cyclopenten-1-yl] ester ,  Acetic acid [(1R,2S)-2-[2-(tert-butyldimethylsiloxy)ethyl]-3-cyclopenten-1-yl] ester ,  Butyric acid [(1R,2S)-2-[2-(tert-butyldimethylsiloxy)ethyl]-3-cyclopenten-1-yl] ester ,  Decanoic acid [(1R,2S)-2-[2-(tert-butyldimethylsiloxy)ethyl]-3-cyclopenten-1-yl] ester ,  Chloroacetic acid [(1R,2S)-2-[2-(tert-butyldimethylsiloxy)ethyl]-3-cyclopenten-1-yl] ester ,  Pivalic acid [(1R,2S)-2-[2-(tert-butyldimethylsiloxy)ethyl]-3-cyclopenten-1-yl] ester ,  Benzoic acid [(1R,2S)-2-[2-(tert-butyldimethylsiloxy)ethyl]-3-cyclopenten-1-yl] ester

Terms in the title (8)： リパーゼ ,  エステル交換 ,  置換 ,  3-シクロペンテン-1-オール ,  ラセミ体 ,  速度論的分割 ,  エナンチオ選択性 ,  戦略