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J-GLOBAL ID：200902187113558789   Reference number：96A0402442

Dioxopyrrolines. LX. Cycloaddition Reaction of 4-Benzoyl-5-ethoxycarbonyl-1-phenyl-1H-pyrrole-2,3-dione to Olefins: An Inverse-Electron-Demand Hetero Diels-Alder Reaction.

ジオキソピロリン類 LX オレフィンへの4-ベンゾイル-5-エトキシカルボニル-1-フェニル-1H-ピロール-2,3-ジオンの環状付加反応 逆電子要求ヘテロDiels-Alder反応

Author (3)： HORIGUCHI Y (Showa Coll. Pharmaceutical Sci., Tokyo, JPN) ,  SANO T (Showa Coll. Pharmaceutical Sci., Tokyo, JPN) ,  TSUDA Y (Univ. Kanazawa, Kanazawa, JPN)
Material： Chemical and Pharmaceutical Bulletin  (Chemical & Pharmaceutical Bulletin)
Volume： 44  Issue： 4  Page： 670-674  Publication year： Apr. 1996 
JST Material Number： G0504A  ISSN： 0009-2363  CODEN： CPBTAL  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： Diels-Alder reaction ,...
Semi thesaurus term： dihydrofurans ,...

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JST classification (2)： Pyrroles  (CF07076L) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (15)： 1-Phenyl-3-benzoyl-4,5-dioxo-2-pyrroline-2-carboxylic acid ethyl ester ,  1,4-Diphenyl-2,3-dioxo-6β-ethoxy-2,3,6,7-tetrahydropyrano[4,3-b]pyrrole-7aα(1H)-carboxylic acid ethyl ester ,  1,4,6β-Triphenyl-2,3-dioxo-2,3,6,7-tetrahydropyrano[4,3-b]pyrrole-7aα(1H)-carboxylic acid ethyl ester ,  1,4-Diphenyl-2,3-dioxo-6β-acetoxy-2,3,6,7-tetrahydropyrano[4,3-b]pyrrole-7aα(1H)-carboxylic acid ethyl ester ,  1,4-Diphenyl-2,3-dioxo-6β-butyl-2,3,6,7-tetrahydropyrano[4,3-b]pyrrole-7aα(1H)-carboxylic acid ethyl ester ,  1,4-Diphenyl-2,3-dioxo-6β-acetoxy-6-methyl-2,3,6,7-tetrahydropyrano[4,3-b]pyrrole-7aα(1H)-carboxylic acid ethyl ester ,  1,4,6β-Triphenyl-2,3-dioxo-6-(trimethylsiloxy)-2,3,6,7-tetrahydropyrano[4,3-b]pyrrole-7aα(1H)-carboxylic acid ethyl ester ,  1,4-Diphenyl-2,3-dioxo-2,3,5aα,7,8,8aα-hexahydro-5,6-dioxa-1-aza-as-indacene-8bα(1H)-carboxylic acid ethyl ester ,  1,4-Diphenyl-2,3-dioxo-2,3,5aα,8,9,9aα-hexahydro-7H-pyrano[3′,2′:5,6]pyrano[4,3-b]pyrrole-9bα(1H)-carboxylic acid ethyl ester ,  1,4-Diphenyl-2,3-dioxo-2,3,5aα,7,8,8aα-hexahydro-6H-cyclopenta[5,6]pyrano[4,3-b]pyrrole-8bα(1H)-carboxylic acid ethyl ester ,  1,4-Diphenyl-2,3-dioxo-2,3,5aα,6,7,8,9,9aα-octahydro-[1]benzopyrano[4,3-b]pyrrole-9bα(1H)-carboxylic acid ethyl ester ,  1,4-Diphenyl-2,3-dioxo-5aα-(trimethylsiloxy)-2,3,5a,7,8,8aα-hexahydro-6H-cyclopenta[5,6]pyrano[4,3-b]pyrrole-8bα(1H)-carboxylic acid ethyl ester ,  1,4-Diphenyl-2,3-dioxo-5aα-(trimethylsiloxy)-2,3,5a,6,7,8,9,9aα-octahydro-[1]benzopyrano[4,3-b]pyrrole-9bα(1H)-carboxylic acid ethyl ester ,  1-Phenyl-2-(2-oxocyclopentyl)-3-benzoyl-4-hydroxy-5-oxo-3-pyrroline-2β-carboxylic acid ethyl ester ,  1-Phenyl-2-(2-oxocyclohexyl)-3-benzoyl-4-hydroxy-5-oxo-3-pyrroline-2β-carboxylic acid ethyl ester

Reference (21)：

• SANO, T. Chem. Pharm. Bull. 1994, 42, 1373
• TSUDA, Y. Heterocycles. 1976, 4, 1237
• SANO, T. Chem. Pharm. Bull. 1987, 35, 9
• SANO, T. Chem. Pharm. Bull. 1987, 35, 4730
• SANO, T. Chem. Pharm. Bull. 1990, 38, 366

Terms in the title (6)： オレフィン ,  1-フェニル-1H-ピロール ,  ジオン ,  環状付加反応 ,  電子 ,  ヘテロDiels-Alder反応