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J-GLOBAL ID：200902188717427573   Reference number：01A0317329

Direct Observation of 2-(1-Methoxycarbonylnaphthyl)methyl Radical via Photo-Claisen Type Rearrangement.

光-Claisen型転位を経由する2-(1-メトキシカルボニルナフチル)メチルラジカルの直接観察

Author (6)： YOSHIMI Y (Osaka Prefecture Univ., Osaka) ,  MIZUNO K (Osaka Prefecture Univ., Osaka) ,  MAEDA H (Osaka Prefecture Univ., Osaka) ,  ICHINOSE N (Japan Atomic Energy Res. Inst., Osaka) ,  TANNAKA T (Japan Atomic Energy Res. Inst., Osaka) ,  KAWANISHI S (Japan Atomic Energy Res. Inst., Osaka)
Material： Chemistry Letters  (Chem Lett)
Issue： 3  Page： 252-253  Publication year： Mar. 05, 2001 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *Claisen rearrangement ,...

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JST classification (2)： Naphthalenes  (CF06020D) ,  Photochemical reaction,radical reaction  (CF02090A)

Substance index (23)： Phenol ,  2-(Phenoxymethyl)-1-naphthoic acid methyl ester ,  2-(2-Hydroxybenzyl)-1-naphthoic acid methyl ester ,  2-(4-Phenylphenoxymethyl)-1-naphthoic acid methyl ester ,  2-(4-Phenyl-2-hydroxybenzyl)-1-naphthoic acid methyl ester ,  2-(4-Methylphenoxymethyl)-1-naphthoic acid methyl ester ,  2-(4-Methyl-2-hydroxybenzyl)-1-naphthoic acid methyl ester ,  2-(4-Cyanophenoxymethyl)-1-naphthoic acid methyl ester ,  2-(4-Cyano-2-hydroxybenzyl)-1-naphthoic acid methyl ester ,  2-(4-Bromophenoxymethyl)-1-naphthoic acid methyl ester ,  2-(4-Bromo-2-hydroxybenzyl)-1-naphthoic acid methyl ester ,  2-(4-Methoxyphenoxymethyl)-1-naphthoic acid methyl ester ,  2-(4-Methoxy-2-hydroxybenzyl)-1-naphthoic acid methyl ester ,  2-(4-Hydroxybenzyl)-1-naphthoic acid methyl ester ,  2-Methyl-1-naphthoic acid methyl ester ,  2,2′-Ethylenebis(1-naphthoic acid methyl) ester ,  Biphenyl-4-ol ,  p-Kresol ,  4-Hydroxybenzonitrile ,  4-Bromophenol ,  4-Methoxyphenol ,  [1-(Methoxycarbonyl)-2-naphthyl]methylradical ,  2-(Bromomethyl)-1-naphthoic acid methyl ester

Reference (27)：

• KROPP, P. J. Acc. Chem. Res. 1984, 17, 131
• DAS, P. K. Chem. Rev. 1993, 93, 119
• PINCOCK, J. A. Acc. Chem. Res. 1997, 30, 43
• ADAM, W. J. Org. Chem. 1973, 38, 2571
• NAKAGAKI, R. J. Phys. Chem. 1985, 89, 3222

Terms in the title (2)： 転位 ,  メチルラジカル