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J-GLOBAL ID：200902189839419950   Reference number：02A0664218

Stereoselective synthesis of 1,2- and 1,4-dihydropyridines by using cation-π interaction as a conformation-controlling tool.

立体配座制御ツールとしてカチオン-π相互作用を使う,1,2-,および1,4-ジヒドロピリジン類の立体選択的合成

Author (3)： YAMADA S (Ochanomizu Univ., Tokyo, JPN) ,  SAITOH M (Ochanomizu Univ., Tokyo, JPN) ,  MISONO T (Ochanomizu Univ., Tokyo, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 43  Issue： 33  Page： 5853-5857  Publication year： Aug. 12, 2002 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...
Semi thesaurus term： chirality

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JST classification (2)： Pyridines  (CF07095Q) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (46)： (3aα,6aα)-1-(4-Pyridyl)-6-(2-naphthylmethyl)octahydrocyclopenta[b]pyrrole-6β-ol ,  3-[[(3aα,6aα)-6β-Hydroxy-6-benzyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]pyridinium-1-carboxylic acid methyl ester ,  (3aα,6aα)-1-Benzyloctahydrocyclopenta[b]pyrrole-6-one ,  (3aα,6aα)-1-[(R)-α-Methylbenzyl]octahydrocyclopenta[b]pyrrole-6-one ,  (3aα,6aα)-Octahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-6-Methyloctahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-6-Phenyloctahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-6-Benzyloctahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-6-(2-Naphthylmethyl)octahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-1-(3-Pyridinylcarbonyl)octahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-1-(3-Pyridinylcarbonyl)-6-methyloctahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-1-(3-Pyridinylcarbonyl)-6-phenyloctahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-1-(3-Pyridinylcarbonyl)-6-benzyloctahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-1-(3-Pyridinylcarbonyl)-6-(2-naphthylmethyl)octahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-1-(1-Methylpyridinium-3-ylcarbonyl)octahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-1-(1-Methylpyridinium-3-ylcarbonyl)-6-methyloctahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-1-(1-Methylpyridinium-3-ylcarbonyl)-6-phenyloctahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-1-(1-Methylpyridinium-3-ylcarbonyl)-6-benzyloctahydrocyclopenta[b]pyrrole-6β-ol ,  (3aα,6aα)-1-(1-Methylpyridinium-3-ylcarbonyl)-6-(2-naphthylmethyl)octahydrocyclopenta[b]pyrrole-6β-ol ,  (3aβ,6aβ)-1-[(R)-α-Methylbenzyl]octahydrocyclopenta[b]pyrrole-6-one ,  (3aβ,6aβ)-6-(2-Naphthylmethyl)octahydrocyclopenta[b]pyrrole-6α-ol ,  (3aβ,6aβ)-1-(3-Pyridinylcarbonyl)-6-(2-naphthylmethyl)octahydrocyclopenta[b]pyrrole-6α-ol ,  Dimethylketene methyl(trimethylsilyl)acetal ,  (4S)-α,α-Dimethyl-1-(methoxycarbonyl)-3-[[(3aα,6aα)-6β-hydroxyoctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,4-dihydropyridine-4β-acetic acid methyl ester ,  (4S)-α,α-Dimethyl-1-(methoxycarbonyl)-3-[[(3aα,6aα)-6β-hydroxy-6-methyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,4-dihydropyridine-4β-acetic acid methyl ester ,  (4S)-α,α-Dimethyl-1-(methoxycarbonyl)-3-[[(3aα,6aα)-6β-hydroxy-6-phenyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,4-dihydropyridine-4β-acetic acid methyl ester ,  (4S)-α,α-Dimethyl-1-(methoxycarbonyl)-3-[[(3aα,6aα)-6β-hydroxy-6-benzyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,4-dihydropyridine-4β-acetic acid methyl ester ,  (4S)-α,α-Dimethyl-1-(methoxycarbonyl)-3-[[(3aα,6aα)-6β-hydroxy-6-(2-naphthylmethyl)octahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,4-dihydropyridine-4β-acetic acid methyl ester ,  (2S)-α,α-Dimethyl-1-(methoxycarbonyl)-5-[[(3aα,6aα)-6β-hydroxyoctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-2α-acetic acid methyl ester ,  (2S)-α,α-Dimethyl-1-(methoxycarbonyl)-5-[[(3aα,6aα)-6β-hydroxy-6-methyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-2α-acetic acid methyl ester ,  (2S)-α,α-Dimethyl-1-(methoxycarbonyl)-5-[[(3aα,6aα)-6β-hydroxy-6-phenyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-2α-acetic acid methyl ester ,  (2S)-α,α-Dimethyl-1-(methoxycarbonyl)-5-[[(3aα,6aα)-6β-hydroxy-6-benzyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-2α-acetic acid methyl ester ,  (2S)-α,α-Dimethyl-1-(methoxycarbonyl)-5-[[(3aα,6aα)-6β-hydroxy-6-(2-naphthylmethyl)octahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-2α-acetic acid methyl ester ,  Allyltributylstannane ,  2-Allyl-3-[[(3aα,6aα)-6β-hydroxyoctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-1-carboxylic acid methyl ester ,  2-Allyl-3-[[(3aα,6aα)-6β-hydroxy-6-methyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-1-carboxylic acid methyl ester ,  2-Allyl-3-[[(3aα,6aα)-6β-hydroxy-6-phenyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-1-carboxylic acid methyl ester ,  2-Allyl-3-[[(3aα,6aα)-6β-hydroxy-6-benzyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-1-carboxylic acid methyl ester ,  2-Allyl-3-[[(3aα,6aα)-6β-hydroxy-6-(2-naphthylmethyl)octahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-1-carboxylic acid methyl ester ,  2-Allyl-5-[[(3aα,6aα)-6β-hydroxyoctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-1-carboxylic acid methyl ester ,  2-Allyl-5-[[(3aα,6aα)-6β-hydroxy-6-methyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-1-carboxylic acid methyl ester ,  2-Allyl-5-[[(3aα,6aα)-6β-hydroxy-6-phenyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-1-carboxylic acid methyl ester ,  2-Allyl-5-[[(3aα,6aα)-6β-hydroxy-6-benzyloctahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-1-carboxylic acid methyl ester ,  2-Allyl-5-[[(3aα,6aα)-6β-hydroxy-6-(2-naphthylmethyl)octahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,2-dihydropyridine-1-carboxylic acid methyl ester ,  (4R)-α,α-Dimethyl-1-(methoxycarbonyl)-3-[[(3aα,6aα)-6β-hydroxy-6-(2-naphthylmethyl)octahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,4-dihydropyridine-4α-acetic acid methyl ester ,  (4R)-α,α-Dimethyl-1-(methoxycarbonyl)-3-[[(3aβ,6aβ)-6α-hydroxy-6-(2-naphthylmethyl)octahydrocyclopenta[b]pyrrole-1-yl]carbonyl]-1,4-dihydropyridine-4α-acetic acid methyl ester

Terms in the title (5)： 立体配座制御 ,  ツール ,  カチオン-π相互作用 ,  ジヒドロピリジン類 ,  立体選択的合成