Art

J-GLOBAL ID：200902192288554500   Reference number：99A0801951

Chloromethanesulfonate as an Efficient Leaving Group: Rearrangement of the Carbon-Carbon Bond and Conversion of Alcohols into Azides and Nitriles.

効率よい脱離基としてのクロロメタンスルホナート 炭素-炭素結合の転位反応とアルコールのアジド及びニトリルへの変換

Author (5)： SHIMIZU T (Inst. Physical and Chemical Res. (RIKEN), Saitama, JPN) ,  OHZEKI T (Inst. Physical and Chemical Res. (RIKEN), Saitama, JPN) ,  HIRAMOTO K (Inst. Physical and Chemical Res. (RIKEN), Saitama, JPN) ,  HORI N (Inst. Physical and Chemical Res. (RIKEN), Saitama, JPN) ,  NAKATA T (Inst. Physical and Chemical Res. (RIKEN), Saitama, JPN)
Material： Synthesis  (Journal of Synthetic Organic Chemistry)
Issue： 8  Page： 1373-1385  Publication year： Aug. 1999 
JST Material Number： D0738A  ISSN： 0039-7881  CODEN： SYNTBF  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *rearrangement reaction ,...

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JST classification (2)： Aromatic monocyclic hydroxy compounds  (CF05070Z) ,  Steroids  (CF10040O)

Substance index (38)： Acetic acid cesium ,  Zinc Acetate ,  (2R,5S)-6′β-(Chloromethylsulfonyloxy)-4,4′aα,5,5′,6′,7′,8′,8′a-octahydro-2′,5,5′,5′,8′aβ-pentamethylspiro[furan-2(3H),1′(4′H)-naphthalene]-5-acetic acid methyl ester ,  (2R,5S)-4,4′aα,5,5′,6′,7′,8′,8′a-Octahydro-2′,5,6′α,8′aβ-tetramethyl-5′-methylenespiro[furan-2(3H),1′(4′H)-naphthalene]-5-acetic acid methyl ester ,  (2R,5S)-4,4′aα,5,7′,8′,8′a-Hexahydro-2′,5,5′,6′,8′aβ-pentamethylspiro[furan-2(3H),1′(4′H)-naphthalene]-5-acetic acid methyl ester ,  (2R,5S)-4,5,6′,7′,8′,8′a-Hexahydro-2′,5,5′,6′α,8′aβ-pentamethylspiro[furan-2(3H),1′(4′H)-naphthalene]-5-acetic acid methyl ester ,  (2R,5S)-1′β-Isopropenyl-1′,2′,3′,3′a,4,5,7′,7′aα-octahydro-3′aβ,5,5′-trimethylspiro[furan-2(3H),4′-[4H]indene]-5-acetic acid methyl ester ,  (2R,5S)-1′β-(1-Hydroxy-1-methylethyl)-1′,2′,3′,3′a,4,5,7′,7′aα-octahydro-3′aβ,5,5′-trimethylspiro[furan-2(3H),4′-[4H]indene]-5-acetic acid methyl ester ,  (2R,5S)-4,4′aα,5,5′,8′,8′a-Hexahydro-2′,5,5′,5′,8′aβ-pentamethylspiro[furan-2(3H),1′(4′H)-naphthalene]-5-acetic acid methyl ester ,  (1S)-1,4aβ-Dimethyl-2β-(chloromethylsulfonyloxy)-5-oxo-1,2,3,4,4a,5,6,7-octahydronaphthalene-1α-acetonitrile ,  (2S)-1-Methylene-4aβ-methyl-5-oxo-1,2,3,4,4a,5,6,7-octahydronaphthalene-2α-acetonitrile ,  (2R,5S)-5-[2-(tert-Butyldiphenylsiloxy)ethyl]-6′α-(chloromethylsulfonyloxy)-4,4′aα,5,5′,6′,7′,8′,8′a-octahydro-2′,5,5′,5′,8′aβ-pentamethylspiro[furan-2(3H),1′(4′H)-naphthalene] ,  (2R,5S)-5-[2-(tert-Butyldiphenylsiloxy)ethyl]-4,4′aα,5,7′,8′,8′a-hexahydro-2′,5,5′,6′,8′aβ-pentamethylspiro[furan-2(3H),1′(4′H)-naphthalene] ,  (2R,5S)-5-[2-(tert-Butyldiphenylsiloxy)ethyl]-4,4′aα,5,5′,8′,8′a-hexahydro-2′,5,5′,5′,8′aβ-pentamethylspiro[furan-2(3H),1′(4′H)-naphthalene] ,  17α-(Chloromethylsulfonyloxy)androsta-4-ene-3-one ,  17-Methyl-18-norandrosta-4,13(17)-dien-3-one ,  17β-Methyl-18-norandrosta-4,13-diene-3-one ,  17β-Methyl-18-norandrosta-4,12-diene-3-one ,  12α-(Chloromethylsulfonyloxy)-3-oxo-5β-cholan-24-oic acid methyl ester ,  12β-Methyl-3-oxo-18-nor-5β-chola-13(17)-ene-24-oic acid methyl ester ,  12β-Methyl-3-oxo-18-nor-5β-chola-13-ene-24-oic acid methyl ester ,  3-Oxo-5β-chol-11-en-24-oic acid methyl ester ,  11α-(Chloromethylsulfonyloxy)-17β-acetylandrost-4-en-3-one ,  11-Dehydroprogesterone ,  Testosterone chloromethanesulfonate ,  17α-Azidoandrosta-4-ene-3-one ,  3-Methoxy-17β-(chloromethylsulfonyloxy)estra-1,3,5(10)-triene ,  3-Methoxy-17α-azidoestra-1,3,5(10)-triene ,  5α-Cholestan-3β-ol chloromethanesulfonate ,  3α-Azido-5α-cholestane ,  1β-Methyl-3β-(chloromethylsulfonyloxy)-4α-isopropylcyclohexane ,  1β-Methyl-3α-azido-4α-isopropylcyclohexane ,  (1R,4S)-p-Mentha-2-ene ,  (2S,3R)-1-(tert-Butyldiphenylsiloxy)-2-phenyl-3-(chloromethylsulfonyloxy)-4-(benzyloxy)butane ,  (2S,3S)-1-(tert-Butyldiphenylsiloxy)-2-phenyl-3-azido-4-(benzyloxy)butane ,  (2R)-2α-(Benzyloxymethyl)-3β-(benzyloxy)-6β-(trimethylsiloxy)-6-methyl-7α-(chloromethylsulfonyloxymethyl)oxepane ,  (2R)-2α-(Benzyloxymethyl)-3β-(benzyloxy)-6β-(trimethylsiloxy)-6-methyl-7α-(cyanomethyl)oxepane ,  (2R)-2α-(Benzyloxymethyl)-3β-(benzyloxy)-6α-methyl-6-hydroxyoxepane-7α-acetonitrile

Terms in the title (6)： 脱離基 ,  炭素-炭素結合 ,  転位反応 ,  アルコール ,  アジド ,  ニトリル