Art

J-GLOBAL ID：200902193815449856   Reference number：00A0111209

Stereoselective alkynylation of trans-2,3-epoxy sulfides with double inversion of configuration by alkynylaluminums.

trans-2,3-エポキシスルフィドのアルキニルアルミニウムによる立体配置の二重反転を伴う立体選択的アルキニル化

Author (4)： SASAKI M (Hokkaido Univ., Sapporo, JPN) ,  MIYAZAWA M (Hokkaido Univ., Sapporo, JPN) ,  TANINO K (Hokkaido Univ., Sapporo, JPN) ,  MIYASHITA M (Hokkaido Univ., Sapporo, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 40  Issue： 52  Page： 9267-9270  Publication year： Dec. 24, 1999 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *alkynylation ,...

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JST classification (1)： Three-membered heterocyclic compounds  (CF07050R)

Substance index (25)： rel-2β^*-(Phenylthiomethyl)-3α^*-propyloxirane ,  1-Hexynyldiethylaluminum ,  (4R,5S)-5-(Phenylthiomethyl)-6-undecyne-4-ol ,  (4R,5S)-5-(Phenylthio)-7-dodecyne-4-ol ,  Hexane ,  Toluene ,  Methylene chloride ,  Trimethylsilylethynyldimethylaluminum ,  rel-2β^*-(Phenylthiomethyl)-3α^*-hexyloxirane ,  rel-2β^*-(Phenylthiomethyl)-3α^*-(benzyloxymethyl)oxirane ,  rel-2α^*-(Phenylthiomethyl)-3α^*-propyloxirane ,  (3R,4R)-1-(Trimethylsilyl)-3-(phenylthiomethyl)-1-heptyne-4-ol ,  (4R,5S)-5-(Phenylthio)-8-(trimethylsilyl)-7-octyne-4-ol ,  (3S,4R)-1-(Trimethylsilyl)-3-(phenylthiomethyl)-1-decyne-4-ol ,  (4S,5R)-1-(Trimethylsilyl)-4-(phenylthio)-1-undecyne-5-ol ,  (7R,8S)-8-(Phenylthiomethyl)-9-tetradecyne-7-ol ,  (7R,8S)-8-(Phenylthio)-10-pentadecyne-7-ol ,  (2S,3S)-1-(Benzyloxy)-3-(phenylthiomethyl)-5-(trimethylsilyl)-4-pentyne-2-ol ,  (2R,3S)-1-(Benzyloxy)-3-(phenylthio)-6-(trimethylsilyl)-5-hexyne-2-ol ,  (2S,3S)-1-(Benzyloxy)-3-(phenylthiomethyl)-4-nonyne-2-ol ,  (2R,3S)-1-(Benzyloxy)-3-(phenylthio)-5-decyne-2-ol ,  (3S,4R)-1-(Trimethylsilyl)-3-(phenylthiomethyl)-1-heptyne-4-ol ,  (4R,5R)-5-(Phenylthio)-8-(trimethylsilyl)-7-octyne-4-ol ,  (4R,5R)-5-(Phenylthiomethyl)-6-undecyne-4-ol ,  (4R,5R)-5-(Phenylthio)-7-dodecyne-4-ol

Terms in the title (4)： 立体配置 ,  反転 ,  立体 ,  アルキニル化