Art

J-GLOBAL ID：200902194863097364   Reference number：02A0587482

Total synthesis of (-)-stevastelin B.

(-)-ステバステリンBの全合成

Author (3)： KUROSAWA K (Keio Univ., Yokohama, JPN) ,  NAGASE T (Keio Univ., Yokohama, JPN) ,  CHIDA N (Keio Univ., Yokohama, JPN)
Material： Chemical Communications  (ChemComm)
Issue： 12  Page： 1280-1281  Publication year： Jun. 21, 2002 
JST Material Number： D0376B  ISSN： 1359-7345  CODEN： CHCOFS  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *Penicillium ,...

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JST classification (2)： Eight or more-membered heterocyclic compounds  (CF07120T) ,  Basic research of immunotherapeutic agents and blood preparations  (GW22010D)

Substance index (20)： Stevastelin B ,  L-Quebrachitol ,  (1R)-1β-Methoxy-2α,3α-epoxy-4α,5α-(isopropylidenedioxy)-6α-methylcyclohexane ,  (1S)-2α,3α-(Isopropylidenedioxy)-4α,6β-dimethyl-5β-methoxycyclohexane-1α-ol ,  (2R)-2α,3α-(Isopropylidenedioxy)-4α,6β-dimethyl-5β-methoxycyclohexanone ,  (2R,3R,4S,5S)-3,5-Dimethyl-4-methoxyhexane-1,2,6-triol triacetate ,  (2R,3R,4S,5S)-1,6-Bis(pivaloyloxy)-2-(methylsulfonyloxy)-3,5-dimethyl-4-methoxyhexane ,  (3R,4R,5R,6R,7S)-3,5-Dimethyl-4-methoxy-6,7-(isopropylidenedioxy)oxepane-2-one ,  (2R,3S,4S)-2-[(S)-Oxirane-2-yl]-3-methoxy-4-methyl-5-(pivaloyloxy)pentane ,  (2S,3S,4S,5R)-2,4-Dimethyl-3-methoxyoctadecane-1,5-diol ,  (2S,3S,4S,5R)-2,4-Dimethyloctadecane-1,3,5-triol ,  (2S,3R)-2-[(4S,5S)-2,2,5-Trimethyl-1,3-dioxane-4-yl]hexadecane-3-ol ,  (2S)-2-(Benzyloxycarbonylamino)-3-(benzyloxy)propanoic acid (1R)-1-[(1S)-1-[(4S,5S)-2,2,5-trimethyl-1,3-dioxane-4-yl]ethyl]tetradecyl ester ,  (2S,3R)-2-[[(2S)-2-(tert-Butyloxycarbonylamino)-3-methylbutanoyl]amino]-3-hydroxybutanoic acid ,  (2S)-2-[[(2S,3R)-2-[[(2S)-2-(tert-Butyloxycarbonylamino)-3-methylbutanoyl]amino]-3-hydroxybutanoyl]amino]-3-(benzyloxy)propanoic acid (1R)-1-[(1S)-1-[(4S,5S)-2,2,5-trimethyl-1,3-dioxane-4-yl]ethyl]tetradecyl ester ,  Boc-L-Val-L-Thr-O-Benzyl-L-Ser-[(R)-1-[(1R,2S,3S)-1,3-dimethyl-2,4-dihydroxybutyl]tetradecyl]OH ,  (2R,3R,4S,5R)-2,4-Dimethyl-3-hydroxy-5-[[(2S)-2-[[(2S,3R)-2-[[(2S)-2-(tert-butyloxycarbonylamino)-3-methylbutanoyl]amino]-3-hydroxybutanoyl]amino]-3-(benzyloxy)propanoyl]oxy]octadecanoic acid ,  (2R,3R,4S,5R)-2,4-Dimethyl-3-hydroxy-5-[[(2S)-2-[[(2S,3R)-2-[[(2S)-2-amino-3-methylbutanoyl]amino]-3-hydroxybutanoyl]amino]-3-(benzyloxy)propanoyl]oxy]octadecanoic acid ,  Cyclo[L-Thr-O-benzyl-L-Ser-[(2R,3R,4R,5R)-2,4-dimethyl-3-hydroxy-5-hydroxyoctadecanoyl]-L-Val-] ,  (3S,6S,9S,12R,13R,14R,15R)-3-(Hydroxymethyl)-6-[(1R)-1-hydroxyethyl]-9-isopropyl-12,14-dimethyl-13-hydroxy-15-tridecyl-1-oxa-4,7,10-triazacyclopentadecane-2,5,8,11-tetrone

Terms in the title (2)： ステバステリンB ,  全合成