Art

J-GLOBAL ID：200902195665516331   Reference number：02A0165484

Reactions of Oxalyl Chloride with 1,2-Cycloalkanediols in the Presence of Triethylamine.

トリチルアミン存在下におけるオキサリルクロリドの1,2-シクロアルカンジオール類との反応

Author (4)： ITAYA T (Kanazawa Univ., Kanazawa, JPN) ,  IIDA T (Kanazawa Univ., Kanazawa, JPN) ,  NATSUTANI I (Kanazawa Univ., Kanazawa, JPN) ,  OHBA M (Kanazawa Univ., Kanazawa, JPN)
Material： Chemical and Pharmaceutical Bulletin  (Chemical & Pharmaceutical Bulletin)
Volume： 50  Issue： 1  Page： 83-86  Publication year： Jan. 01, 2002 
JST Material Number： G0504A  ISSN： 0009-2363  CODEN： CPBTAL  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *esterification ,...

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JST classification (2)： Addition reaction,elimination reaction  (CF02030M) ,  7 or more-membered monocyclic alicyclic compounds  (CF04060H)

Substance index (29)： Triethylamine ,  Pinacol ,  Oxalyl chloride ,  4,4,5,5-Tetramethyl-1,3-dioxolan-2-one ,  1,1,2-Trimethyl-2-(chlorocarbonyloxy)-1-propanolanion ,  5,5,6,6-Tetramethyl-1,4-dioxane-2,3-dione ,  Chlorooxoacetic acid 1,1,2-trimethyl-2-hydroxypropyl ester ,  3α-Chloro-3-hydroxy-5,5,6,6-tetramethyl-1,4-dioxane-2-one ,  2-Chloro-3-oxo-5,5,6,6-tetramethyl-1,4-dioxane-2α-olanion ,  1α,2α-Cyclohexanediol ,  (4S,5R)-4β,5β-Butano-1,3-dioxolane-2-one ,  Oxalic acid 1α,2α-cyclohexanediyl ester ,  1α,2α-Cyclopentanediol ,  1β,2β-(Epoxymethanoxy)cyclopentane-7-one ,  Oxalic acid 1α,2α-cyclopentanediyl ester ,  Cyclooctane-1α,2α-diol ,  Carbonic acid 1α,2α-cyclooctanediyl ester ,  Oxalic acid 1α,2α-cyclooctanediyl ester ,  rac-1α^*,2β^*-Cyclohexanediol ,  rac-Chlorooxoacetic acid 2β^*-hydroxycyclohexane-1α^*-yl ester ,  rac-Oxalic acid 1α^*,2β^*-cyclohexanediyl ester ,  rac-1α^*,2β^*-Cyclopentanediol ,  rac-(4aα^*,7aβ^*)-Hexahydro-5H-cyclopenta-1,4-dioxin-2,3-dione ,  (±)-trans-1,2-cycloheptanediol ,  rac-(3aα^*,8aβ^*)-Hexahydro-4H-cyclohepta-1,3-dioxole-2-one ,  rac-(4aα^*,9aβ^*)-Octahydro-5H-cyclohepta-1,4-dioxin-2,3-dione ,  rac-1α^*,2β^*-Cyclooctanediol ,  rac-(3aα^*,9aβ^*)-Octahydrocycloocta-1,3-dioxole-2-one ,  rac-(4aα^*,10aβ^*)-Decahydrocycloocta-1,4-dioxin-2,3-dione

Reference (10)：

• 1) Itaya T., Iida T., Eguchi H., Chem. Pharm. Bull., 41, 408—410 (1993).
• 2) Iida T., Itaya T., Tetrahedron, 49, 10511—10530 (1993).
• 3) No trace of 12b was formed in the reaction of 9b with an excess of triphosgene in dichloromethane in the presence of pyridine at room temperature for 9 h.
• 4) Nicolaou K. C., Sorensen E. J., Discordia R., Hwang C.-K., Minto R. E., Bharucha K. N., Bergman R. G., Angew. Chem. Int. Ed. Engl., 31, 1044—1046 (1992).
• 5) Kruper W. J., Dellar D. V., J. Org. Chem., 60, 725—727 (1995).

Terms in the title (2)： トリチルアミン ,  オキサリルクロリド