Art

J-GLOBAL ID：200902197525209326   Reference number：01A0138985

New Scheme of the Biosynthesis of Formononetin Involving 2,7,4′-Trihydroxyisoflavanone but Not Daidzein as the Methyl Acceptor.

ダイゼインでなく2,7,4′-トリヒドロキシイソフラバノンをメチル基受容体とするホルモノネチンの新生合成スキーム

Author (4)： AKASHI T (Nihon Univ., Kanagawa, JPN) ,  SAWADA Y (Nihon Univ., Kanagawa, JPN) ,  AOKI T (Nihon Univ., Kanagawa, JPN) ,  AYABE S (Nihon Univ., Kanagawa, JPN)
Material： Bioscience, Biotechnology, and Biochemistry  (Bioscience Biotechnology & Biochemistry)
Volume： 64  Issue： 10  Page： 2276-2279  Publication year： Oct. 23, 2000 
JST Material Number： G0021A  ISSN： 0916-8451  CODEN： BBBIEJ  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *isoflavonoid ,...
Semi thesaurus term： Glycyrrhiza echinata

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JST classification (2)： Metabolism of substances  (EH02050Q) ,  Condensed derivatives of pyrane  (CF07093I)

Substance index (2)： Formononetin ,  Liquiritigenin

Reference (18)：

• 1) Dixon, R. A., Isoflavonoids: biochemistry, molecular biology, and biological functions. In “Comprehensive Natural Products Chemistry. Volume 1. Polyketides and other secondary metabolites including fatty acids and their derivatives”, ed. Sankawa, U., Elsevier, Oxford, pp. 773-823 (1999).
• 2) Crombie, L. and Whiting, D., Biosynthesis in the rotenoid group of natural products: applications of isotope methodology. Phytochemistry, 49, 1479-1507 (1998).
• 3) Smith, D. A. and Banks, S. W., Biosynthesis, elicitation and biological activity of isoflavonoid phytoalexins. Phytochemistry, 25, 979-995 (1986).
• 4) Wengenmayer, H., Ebel, J., and Grisebach, H., Purification and properties of a S-adenosylmethionine: isoflavone 4′-O-methyltransferase from cell suspension cultures of Cicer arietinum L. Eur. J. Biochem., 50, 135-143 (1974).
• 5) Hagmann, M. and Grisebach, H., Enzymatic rearrangement of flavanone to isoflavone. FEBS Lett., 175, 199-202 (1984).

Terms in the title (6)： ダイゼイン ,  メチル基 ,  受容体 ,  ホルモノネチン ,  新生合成 ,  スキーム