Art

J-GLOBAL ID：200902198681789681   Reference number：02A0648309

Highly Enantioselective Intra- and Intermolecular [2+2] Photocycloaddition Reactions of 2-Quinolones Mediated by a Chiral Lactam Host: Host-Guest Interactions, Product Configuration, and the Origin of the Stereoselectivity in Solution.

キラルなラクタムホストにより媒介された2-キノロン類の高エナンチオ選択的分子内および分子間[2+2]光環状付加反応 ホスト-ゲスト相互作用,生成物立体配置,および溶液での立体選択性基原

Author (4)： BACH T (Technische Univ. Muenchen, Gerching, DEU) ,  BERGMANN H (Philipps-Univ. Marburg, Marburg, DEU) ,  GROSCH B (Technische Univ. Muenchen, Gerching, DEU) ,  HARMS K (Philipps-Univ. Marburg, Marburg, DEU)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 124  Issue： 27  Page： 7982-7990  Publication year： Jul. 10, 2002 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...
Semi thesaurus term： stability constant

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JST classification (2)： Quinolines,isoquinolines  (CF07096H) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (24)： (1S)-1α,3α,5α-Trimethyl-5,3-(carbonyliminomethylene)-1-(5,6-butanobenzoxazole-2-yl)cyclohexane ,  1,3-(Carbonyliminomethylene)-5-(5,6-butanobenzoxazole-2-yl)-1α,3α,5α-trimethylcyclohexane ,  4-(Allyloxy)quinoline-2(1H)-one ,  (3S)-4,10β-(Oxymethylene)-3,4-dihydro-3β,4β-ethanoquinoline-2(1H)-one ,  4-(4-Pentenyloxy)-2(1H)-quinolone ,  (1S)-8bβ,1β-(Epoxypropano)-1,2,2aβ,3,4,8b-hexahydrocyclobuta[c]quinoline-3-one ,  (1S)-4-Acetyl-8bβ,1β-(epoxypropano)-1,2,2aβ,3,4,8b-hexahydrocyclobuta[c]quinoline-3-one ,  (1S)-3-Oxo-8bβ,1β-(epoxypropano)-1,2,2aβ,3,4,8b-hexahydrocyclobuta[c]quinoline-4-carboxylic acid (1R)-2α-isopropyl-5β-methylcyclohexane-1β-yl ester ,  4-Methoxy-2(1H)-quinolinone ,  4-Penten-1-ol ,  Acetic acid allyl ,  Acetic acid vinyl ester ,  Styrene ,  Acrylic acid methyl ,  2-Ethyl-1-butene ,  (1R)-1α-(3-Hydroxypropyl)-8bα-methoxy-1,2,2aα,3,4,8b-hexahydrocyclobuta[c]quinoline-3-one ,  (1S)-1α-(Acetoxymethyl)-8bα-methoxy-1,2,2aα,3,4,8b-hexahydrocyclobuta[c]quinoline-3-one ,  (3S)-4-Methoxy-9β-(acetoxymethyl)-3,4-dihydro-3β,4β-ethanoquinoline-2(1H)-one ,  (3S)-4-Methoxy-9β-acetoxy-3,4-dihydro-3β,4β-ethanoquinoline-2(1H)-one ,  (1R)-1α-Acetoxy-8bβ-methoxy-1,2,2aβ,3,4,8b-hexahydrocyclobuta[c]quinoline-3-one ,  (1S)-1α-Phenyl-8bβ-methoxy-1,2,2aβ,3,4,8b-hexahydrocyclobuta[c]quinoline-3-one ,  (1S)-3-Oxo-8bα-methoxy-1,2,2aα,3,4,8b-hexahydrocyclobuta[c]quinoline-1β-carboxylic acid methyl ester ,  (3R)-4-Methoxy-9,9-diethyl-3,4-dihydro-3α,4α-ethanoquinoline-2(1H)-one ,  2-Quinolinol

Terms in the title (9)： キラル ,  ラクタム ,  2-キノロン ,  光環状付加 ,  ホスト-ゲスト相互作用 ,  生成物 ,  立体配置 ,  溶液 ,  立体選択性