Art

J-GLOBAL ID：200902200411062458   Reference number：09A0191871

Tuning the Chiral Environment of C₂-Symmetric Diene Ligands: Development of 3,7-Disubstituted Bicyclo[3.3.1]nona-2,6-dienes

C₂-対称ジエン配位子のキラル環境の調整 3,7-二置換ビシクロ[3.3.1]ノナ-2,6-ジエンの開発

Author (5)： SHINTANI Ryo (Kyoto Univ., Kyoto, JPN) ,  ICHIKAWA Yoshitaka (Kyoto Univ., Kyoto, JPN) ,  TAKATSU Keishi (Kyoto Univ., Kyoto, JPN) ,  CHEN Fu-Xue (Kyoto Univ., Kyoto, JPN) ,  HAYASHI Tamio (Kyoto Univ., Kyoto, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 74  Issue： 2  Page： 869-873  Publication year： Jan. 16, 2009 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *bridged compound ,  ligand ,  optical activity ,  symmetric molecule ,  rhodium catalyst ,  asymmetric reaction ,  addition reaction ,  *unsaturated ketone ,  crystal structure ,  rhodium complex ,  molecular design ,  asymmetric synthesis ,  *organoboron compound ,  catalytic reaction ,  nucleophilic reagent ,  ligand effect ,  addition product
Semi thesaurus term： bridged compound

JST classification (2)： Bridged bicyclic carbocyclic compounds  (CF06100Q) ,  Organoboron compounds  (CF08020R)

Substance index (20)： Bicyclo[3.3.1]nonane-3,7-dione ,  3,7-Bis(trifluoromethylsulfonyloxy)bicyclo[3.3.1]nonane-2,6-diene ,  (1S,5S)-3,7-Diphenylbicyclo[3.3.1]nonane-2,6-diene ,  (1S,5S)-3,7-Bis(4-methoxyphenyl)bicyclo[3.3.1]nonane-2,6-diene ,  (E)-1-Phenyl-3-(dimethylphenylsilyl)-2-propene-1-one ,  (E)-1-Heptenylboronic acid ,  (3S,4E)-1-Phenyl-3-(dimethylphenylsilyl)-4-decene-1-one ,  (3S,4E)-1,7-Diphenyl-3-(dimethylphenylsilyl)-4-heptene-1-one ,  (3S,4E)-1-Phenyl-3-(dimethylphenylsilyl)-5-cyclohexyl-4-pentene-1-one ,  3-[(E)-Styryl]cyclopentanone ,  3-[(E)-Styryl]cyclohexanone ,  3-[(E)-Styryl]cycloheptanone ,  (E)-4-Methyl-6-phenyl-5-hexene-2-one ,  (5E)-4-Propyl-6-phenyl-5-hexene-2-one ,  (E)-4-Isopropyl-6-phenyl-5-hexene-2-one ,  3-Phenylcyclopentanone ,  3-(4-Methoxyphenyl)cyclohexanone ,  3-[4-(Trifluoromethyl)phenyl]cyclohexanone ,  1,8-Dimethyl-2-isobutyl-5-allyl-8-methoxybicyclo[2.2.2]octa-2,5-diene ,  2,5-Dibenzyl-1β,4β-methano-2,5-cyclohexadiene

Terms in the title (8)： C2 ,  対称 ,  ジエン ,  配位子 ,  キラル ,  環境 ,  置換 ,  開発