Art

J-GLOBAL ID：200902201658429997   Reference number：08A0126419

Efficient total syntheses of natural pterin glycosides: limipterin and tepidopterin

天然プテリングリコシドの効率的な全合成 リミプテリン及びテピドプテリン

Author (4)： HANAYA Tadashi (Dep. of Chemistry, Fac. of Sci., Okayama Univ., Tsushima-naka, Okayama 700-8530, JPN) ,  BABA Hiroki (Dep. of Chemistry, Fac. of Sci., Okayama Univ., Tsushima-naka, Okayama 700-8530, JPN) ,  TOYOTA Hiroki (Dep. of Chemistry, Fac. of Sci., Okayama Univ., Tsushima-naka, Okayama 700-8530, JPN) ,  YAMAMOTO Hiroshi (School of Pharmacy, Shujitsu Univ., Okayama 703-8516, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 64  Issue： 9  Page： 2090-2100  Publication year： Feb. 25, 2008 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *glycoside ,  *lactam ,  microorganism ,  secondary metabolite ,  total synthesis ,  asymmetric synthesis ,  *Glycosylation ,  functional group protection ,  deprotection ,  proton magnetic resonance ,  13C NMR ,  silver compound ,  pentose ,  aldose

JST classification (2)： Glycosides  (CF10057O) ,  Microorganism biochemistry  (EG03020N)

Substance index (16)： Xylose ,  L-Xylose ,  Tetramethylurea ,  (4S)-2-Hydroxy-4β-(4-methoxybenzyloxy)-5α-methyltetrahydrofuran-3-one ,  2-Amino-6-[(1R,2S)-1-(4-methoxybenzyloxy)-2-hydroxypropyl]-3,4-dihydropteridine-4-one ,  2-(Dimethylaminomethyleneamino)-3-(4-nitrophenethyl)-6-[(1R,2S)-1-(4-methoxybenzyloxy)-2-acetoxypropyl]-3,4-dihydropteridine-4-one ,  (4R)-2-Hydroxy-4α-(4-methoxybenzyloxy)-5α-methyltetrahydrofuran-3-one ,  2-Amino-6-[(1S,2S)-1-(4-methoxybenzyloxy)-2-hydroxypropyl]-3,4-dihydropteridine-4-one ,  2-(Dimethylaminomethyleneamino)-3-[2-(4-nitrophenyl)ethyl]-6-[(1S,2S)-1-(4-methoxybenzyloxy)-2-acetoxypropyl]-3,4-dihydropteridine-4-one ,  2-[(Dimethylamino)methyleneamino]-3-(4-nitrophenethyl)-6-[(1R,2S)-1-(4-methoxybenzyloxy)-2-hydroxypropyl]pteridine-4(3H)-one ,  2-[(Dimethylamino)methyleneamino]-3-(4-nitrophenethyl)-6-[(1S,2S)-1-(4-methoxybenzyloxy)-2-hydroxypropyl]pteridine-4(3H)-one ,  1-Bromo-2-phthalimidyl-3-O,4-O,6-O-triacetyl-1,2-dideoxy-β-D-glucopyranose ,  2-(Dimethylaminomethyleneamino)-3-[2-(4-nitrophenyl)ethyl]-6-[(1R,2S)-1-(4-methoxybenzyloxy)-2-(2-phthalimidyl-3-O,4-O,6-O-triacetyl-2-deoxy-β-D-glucopyranosyloxy)propyl]-3,4-dihydropteridine-4-one ,  2-(Dimethylaminomethyleneamino)-3-[2-(4-nitrophenyl)ethyl]-6-[(1S,2S)-1-(4-methoxybenzyloxy)-2-(2-phthalimidyl-3-O,4-O,6-O-triacetyl-2-deoxy-β-D-glucopyranosyloxy)propyl]-3,4-dihydropteridine-4-one ,  Limipterin ,  Tepidopterin

Terms in the title (1)： 全合成