Art

J-GLOBAL ID：200902203265290051   Reference number：08A1020431

Rhodium Catalyzed 1,4-Conjugate Addition of 1,5-Azastibocines with Electron Deficient Olefins

ロジウム触媒を用いた1,5-アザスチボシン類と電子不足オレフィン類の1,4-共役付加

Author (2)： KAKUSAWA Naoki (Fac. of Pharmaceutical Sciences, Hokuriku Univ.) ,  KURITA Jyoji (Fac. of Pharmaceutical Sciences, Hokuriku Univ.)
Material： Chemical and Pharmaceutical Bulletin  (Chemical & Pharmaceutical Bulletin)
Volume： 56  Issue： 10  Page： 1502-1504 (J-STAGE)  Publication year： 2008 
JST Material Number： G0504A  ISSN： 0009-2363  CODEN： CPBTAL  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *antimony compound ,  polynuclear aromatic compound ,  *nitrogen heterocyclic compound ,  olefin compound ,  *addition reaction ,  chemical synthesis ,  catalytic reaction ,  rhodium catalyst ,  rhodium complex ,  reaction mechanism ,  optimization ,  water ,  aliphatic ketone ,  vinyl compound ,  unsaturated fatty acid ,  carboxylate(ester)
Semi thesaurus term： conjugate addition

JST classification (2)： Eight or more-membered heterocyclic compounds  (CF07120T) ,  Platinum family element complexes  (CE01100E)

Substance index (17)： Methyl vinyl ketone ,  2-Cyclohexen-1-one ,  3-Phenylcyclohexanone ,  3-Phenylcyclopentanone ,  3-Phenylpropionic acid methyl ,  3-Penten-2-one ,  4-Phenyl-2-butanone ,  N-Methylpyrrolidone ,  Acrylic acid butyl ,  Acrylic acid tert-butyl ,  Acrylic acid methyl ,  [tert-Butyliminobis(methylene 1,2-phenylene)](4-methylphenyl) antimony ,  6-tert-Butyl-12-(4-methoxyphenyl)-5,6,7,12-tetrahydro-6-aza-12-stibadibenzo[a,d]cyclooctene ,  [tert-Butyliminobis(methylene 1,2-phenylene)](4-chlorophenyl) antimony ,  Benzenepropionic acid butyl ester ,  tert-Butyl 3-phenylpropionate ,  3-Phenylbutyric acid methyl ester

Reference (26)：

• NICOLAOU, K. C. Angew. Chem. Int. Ed. 2005, 44, 4442-4489
• LITTKE, A. F. Angew. Chem. Int. Ed. 2002, 41, 4176-4211
• PENA, M. A. Synthesis. 2005, 2005, 485-492
• MIAO, W. Acc. Chem. Res. 2006, 39, 897-908
• HAYNES, B. L. Microwave Synthesis ; Chemistry at the Speed of Light. 2002

Terms in the title (4)： ロジウム触媒 ,  電子 ,  オレフィン類 ,  共役付加