Art

J-GLOBAL ID：200902205417032536   Reference number：04A0916397

Palladium-catalyzed intramolecular α-arylation of aliphatic ketone, formyl, and nitro groups

脂肪族ケトン,ホルミル及びニトロ基のパラジウム触媒による分子内α-アリール化

Author (3)： MURATAKE H (Res. Foundation Itsuu Lab., Tokyo, JPN) ,  NATSUME M (Res. Foundation Itsuu Lab., Tokyo, JPN) ,  NAKAI H (Shionogi & Co. Ltd., Osaka, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 60  Issue： 51  Page： 11783-11803  Publication year： Dec. 13, 2004 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： palladium catalyst ,...
Semi thesaurus term： bridged compound ,...

   To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=04A0916397&from=J-GLOBAL&jstjournalNo=E0234A") }}

JST classification (4)： Monocyclic alicyclic compounds in general  (CF04010E) ,  Aliphatic aldehydes  (CF03180F) ,  Aliphatic nitro and nitroso compounds  (CF03060A) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (24)： Tetralin-1-one ,  Triphenylphosphine ,  2-(2-Bromobenzyl)cyclopentanone ,  2-(2-Bromobenzyl)cyclohexanone ,  2-[3-(2-Bromophenyl)propyl]cyclohexanone ,  1,3-Ethano-1,2,3,4-tetrahydronaphthalene-2-one ,  1,3-Propano-1,2,3,4-tetrahydronaphthalene-2-one ,  Spiro[cyclopentane-1,1′-indan]-2-one ,  Spiro[cyclohexane-1,1′-indan]-2-one ,  Spiro[cyclohexane-1,1′-tetralin]-2-one ,  (6S)-6β-(2-Bromobenzyl)-1,4-dioxaspiro[4.5]decane-7α-carbaldehyde ,  (6S)-6β-(2-Bromobenzyl)-1,4-dioxaspiro[4.5]decane-7α-acetaldehyde ,  (4aR)-3,4,4aα,9,9aβ,10-Hexahydrospiro[anthracene-1(2H),2′-[1,3]dioxolan]-10-one ,  (4aR)-3,4,4a,9aβ-Tetrahydrospiro[9H-fluorene-1(2H),2′-[1,3]dioxolane]-4aβ-carbaldehyde ,  (4aR)-3,4,4a,9,10,10aβ-Hexahydrospiro[phenanthrene-1(2H),2′-[1,3]dioxolane]-4β-carbaldehyde ,  (4aR)-3,4,4aα,10,11,11aβ-Hexahydrospiro[5H-dibenzo[a,d]cycloheptene-1(2H),2′-[1,3]dioxolane]-5-one ,  (4aS)-7-Methoxy-3,4,4a,9,10,10aβ-hexahydrospiro[phenanthrene-1(2H),2′-[1,3]dioxolane]-4α-carbaldehyde ,  (4aR)-8-Methoxy-2,3,4,4aα,5,10,11,11aβ-octahydrospiro[1H-dibenzo[a,d]cycloheptene-1,2′-[1,3]dioxolane]-5-one ,  (4aS)-1,2,3,4aα,5,10,11,11aβ-Octahydrospiro[4H-dibenzo[a,d]cycloheptene-4,2′-[1,3]dioxolan]-10-one ,  1-(4-Nitrobutyl)-2-bromobenzene ,  Spiro[tetralin-1,2′-[1,3]dioxolane]-4-one ,  (4aS)-3,4,4aβ,9,9aβ,10-Hexahydrospiro[anthracene-1(2H),2′-[1,3]dioxolan]-10-one ,  1,2,3,10a-Tetrahydrospiro[phenanthrene-9(10H),2′-[1,3]dioxolane] ,  11-Methyl-5H-dibenzo[a,d]cycloheptene

Terms in the title (5)： 脂肪族ケトン ,  ホルミル ,  ニトロ基 ,  パラジウム触媒 ,  アリール化