Art

J-GLOBAL ID：200902206181651120   Reference number：04A0337545

Studies on the Constituents of Catalpa Species. IX. Iridoids from the Fallen Leaves of Catalpa ovata G. DON

Catalpa種の成分についての研究 IX Catalpa ovata G.DONの落ち葉からのイリドイド

Author (3)： MACHIDA K (Tohoku Pharmaceutical Univ., Miyagi, JPN) ,  HISHINUMA E (Tohoku Pharmaceutical Univ., Miyagi, JPN) ,  KIKUCHI M (Tohoku Pharmaceutical Univ., Miyagi, JPN)
Material： Chemical and Pharmaceutical Bulletin  (Chemical & Pharmaceutical Bulletin)
Volume： 52  Issue： 5  Page： 618-621  Publication year： May. 01, 2004 
JST Material Number： G0504A  ISSN： 0009-2363  CODEN： CPBTAL  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *iridoid ,...
Semi thesaurus term： Catalpa ovata ,...

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JST classification (3)： Monoterpenes,sesquiterpenes  (CF10022A) ,  Animal biochemistry  (EJ01050P) ,  Crude drugs in general  (GX06010Y)

Substance index (24)： (2aS,4aβ,7aβ,7bβ)-4β-(4-Hydroxy-trans-cinnamoyloxy)octahydro-2H-1,7-dioxacyclopenta[cd]indene-2aβ-ol ,  (2aS,4aβ,7aβ,7bβ)-4β-(4-Hydroxy-cis-cinnamoyloxy)octahydro-2H-1,7-dioxacyclopenta[cd]indene-2aβ-ol ,  (2aS,4aβ,7aβ,7bβ)-4β-(4-Hydroxy-trans-cinnamoyloxy)-6α-methoxyoctahydro-2H-1,7-dioxacyclopenta[cd]indene-2aβ-ol ,  (2aS,4aβ,7aβ,7bβ)-4β-(4-Hydroxy-trans-cinnamoyloxy)octahydro-2H-1,7-dioxacyclopenta[cd]indene-2aβ,6α-diol ,  (2aS,4aβ,7aβ,7bβ)-4β-(4-Hydroxy-cis-cinnamoyloxy)-6α-methoxyoctahydro-2H-1,7-dioxacyclopenta[cd]indene-2aβ-ol ,  (2aS,4aβ,7aβ,7bβ)-4β-(4-Hydroxy-cis-cinnamoyloxy)octahydro-2H-1,7-dioxacyclopenta[cd]indene-2aβ,6α-diol ,  (2aS,4aβ,7aβ,7bβ)-4β-(4-Hydroxy-trans-cinnamoyloxy)-6β-methoxyoctahydro-2H-1,7-dioxacyclopenta[cd]indene-2aβ-ol ,  (2aS,4aβ,7aβ,7bβ)-4β-(4-Hydroxy-trans-cinnamoyloxy)octahydro-2H-1,7-dioxacyclopenta[cd]indene-2aβ,6β-diol ,  (2aS,4aβ,7aβ,7bβ)-4β-(4-Hydroxy-cis-cinnamoyloxy)-6β-methoxyoctahydro-2H-1,7-dioxacyclopenta[cd]indene-2aβ-ol ,  (2aS,4aβ,7aβ,7bβ)-4β-(4-Hydroxy-cis-cinnamoyloxy)octahydro-2H-1,7-dioxacyclopenta[cd]indene-2aβ,6β-diol ,  (3S,3aα)-3α-Methoxy-5α-(4-hydroxy-trans-cinnamoyloxy)-6aα-hydroxyhexahydro-1H-cyclopenta[c]furan-4β-acetic acid methyl ester ,  (3S,3aα)-3α,6aα-Dihydroxy-5α-(4-hydroxy-trans-cinnamoyloxy)hexahydro-1H-cyclopenta[c]furan-4β-acetic acid methyl ester ,  (3S,3aα)-3α-Methoxy-5α-(4-hydroxy-cis-cinnamoyloxy)-6aα-hydroxyhexahydro-1H-cyclopenta[c]furan-4β-acetic acid methyl ester ,  (3S,3aα)-3α,6aα-Dihydroxy-5α-(4-hydroxy-cis-cinnamoyloxy)hexahydro-1H-cyclopenta[c]furan-4β-acetic acid methyl ester ,  (4aα,6S,7aα)-6α-[6-O-(4-Hydroxybenzoyl)-β-D-glucopyranosyloxy]-7β-methyloctahydrocyclopenta[c]pyran-1-one ,  (1S)-2α-Methyl-3β-[6-O-(4-hydroxybenzoyl)-β-D-glucopyranosyloxy]-5α-(2-hydroxyethyl)cyclopentane-1α-acetic acid methyl ester ,  (1S)-2α-[[6-O-(4-Hydroxybenzoyl)-β-D-glucopyranosyloxy]methyl]-3-methylene-4β-(4-hydroxybenzoyloxy)cyclopentane-1α-ethanol ,  (2E,6R)-2,6-Dimethyl-8-[6-O-(4-hydroxy-trans-cinnamoyl)-β-D-glucopyranosyloxy]-2-octenoic acid ,  (1S)-1-[6-O-(4-Hydroxybenzoyl)-β-D-glucopyranosyloxy]-5α-(4-hydroxybenzoyloxy)-1,4aα,5,6,7,7aα-hexahydro-6α,7-epoxycyclopenta[c]pyran-7β-methanol ,  Methyl 6-O-(4-hydroxybenzoyl)-β-D-glucopyranoside ,  Ethyl 6-O-(4-hydroxybenzoyl)-β-D-glucopyranoside ,  β-D-Glucopyranose 1,6-bis(4-hydroxybenzoate) ,  Martynoside ,  cis-Martynoside

Reference (18)：

• 1) Part 9 in the series “Studies on the Constituents of Catalpa Species.” For part 8: Machida K., Shioda K., Yaoita Y., Kakuda R., Kikuchi M., Nat. Med., 55, 147—148 (2001).
• 2) Kanai E., Machida K., Kikuchi M., Chem. Pharm. Bull., 44, 1607—1609 (1996).
• 3) Machida K., Ogawa M., Kikuchi M., Chem. Pharm. Bull., 46, 1056—1057 (1998).
• 4) Ikeda C., Machida K., Kakuda R., Yaoita Y., Kikuchi M., J. Tohoku Pharm. Univ., 46, 63—69 (1999).
• 5) Machida K., Ikeda C., Kakuda R., Yaoita Y., Kikuchi M., Nat. Med., 55, 61—63 (2001).

Terms in the title (4)： 研究 ,  DON ,  落ち葉 ,  イリドイド