Art

J-GLOBAL ID：200902206454284258   Reference number：08A0999712

A facile synthesis of 4,6-O-benzylidene-d-glycals via 1,5-anhydro-4,6-O-benzylidene-d-hex-1-en-3-ulose

1,5-アンヒドロ-4,6-O-ベンジリデン-D-ヘキサ-1-エン-3-ウロースを経由する4,6-O-ベンジリデン-D-グリカール類の簡易合成

Author (6)： SAKAKIBARA Tohru (Dep. of Chemistry, Graduate School of Integurated Sci., Yokohama City Univ., Seto Kanazawa-ku, Yokohama 236, JPN) ,  ITO Tsubasa (Dep. of Chemistry, Graduate School of Integurated Sci., Yokohama City Univ., Seto Kanazawa-ku, Yokohama 236, JPN) ,  KOTAKA Chika (Dep. of Chemistry, Graduate School of Integurated Sci., Yokohama City Univ., Seto Kanazawa-ku, Yokohama 236, JPN) ,  KAJIHARA Yasuhiro (Dep. of Chemistry, Graduate School of Integurated Sci., Yokohama City Univ., Seto Kanazawa-ku, Yokohama 236, JPN) ,  WATANABE Yuhya (Dep. of Chemistry, Graduate School of Integurated Sci., Yokohama City Univ., Seto Kanazawa-ku, Yokohama 236, JPN) ,  FUJIOKA Aki (Dep. of Chemistry, Graduate School of Integurated Sci., Yokohama City Univ., Seto Kanazawa-ku, Yokohama 236, JPN)
Material： Carbohydrate Research  (Carbohydr Res)
Volume： 343  Issue： 16  Page： 2740-2743  Publication year： Nov. 03, 2008 
JST Material Number： B0929A  ISSN： 0008-6215  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *unsaturated sugar ,  aromatic compound ,  Sodium tetrahydridoborate ,  reduction (reaction) ,  Acetylation ,  regiospecific reaction ,  diastereomer ,  separation ,  total synthesis ,  monosaccharide ,  *Benzylidene Compounds

JST classification (2)： Monosaccharides  (CF10052H) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (7)： 5β-Hydroxy-6β-(hydroxymethyl)-5,6-dihydro-4H-pyran-4-one ,  (2S)-2β-Phenyl-4aα,8aα-dihydro-4H,8H-pyrano[3,2-d][1,3]dioxin-8-one ,  (2S)-2β-Phenyl-4aα,8aα-dihydro-4H,8H-pyrano[3,2-d][1,3]dioxin-8β-ol ,  1,2-Dideoxy-D-erythro-1-hexenopyranos-3-ulose ,  (2R)-2α-Phenyl-4aα,8aβ-dihydro-4H,8H-pyrano[3,2-d][1,3]dioxin-8-one ,  (2R)-2α-Phenyl-4aα,8aβ-dihydro-4H,8H-pyrano[3,2-d][1,3]dioxin-8β-ol ,  4-O,6-O-[(R)-Benzylidene]-1,5-anhydro-2-deoxy-D-ribo-hexa-1-enitol

Terms in the title (3)： ベンジリデン ,  グリカール ,  簡易