Art

J-GLOBAL ID：200902206509900182   Reference number：03A0770836

Iridium-Catalyzed Direct Borylation of Five-Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions

ビス(ピナコラート)二ほう素による五員環ヘテロアレーンのイリジウム触媒直接ボリル化: 位置特異性,当量性,および室温の反応

Author (5)： ISHIYAMA T (Hokkaido Univ., Sapporo, JPN) ,  TAKAGI J (Hokkaido Univ., Sapporo, JPN) ,  YONEKAWA Y (Hokkaido Univ., Sapporo, JPN) ,  HARTWIG J F (Yale Univ., Connecticut, USA) ,  MIYAURA N (Hokkaido Univ., Sapporo, JPN)
Material： Advanced Synthesis & Catalysis  (Adv Synth Catal)
Volume： 345  Issue： 9/10  Page： 1103-1106  Publication year： Sep. 2003 
JST Material Number： W1343A  ISSN： 1615-4150  CODEN： ASCAF7  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *iridium complex ,...
Semi thesaurus term： iridium catalyst

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JST classification (3)： Organoboron compounds  (CF08020R) ,  Platinum family element complexes  (CE01100E) ,  Catalytic reactions in general  (CB06080F)

Substance index (28)： Methanol ,  1,5-Cyclooctadiene ,  Pinacolborane ,  2-Methylthiophene ,  Furan ,  Thiophene ,  Pyrrole ,  2,2'-Dipyridyl ,  4,4'-Dimethyl-2,2'-bipyridine ,  5,5'-Dimethyl-2,2'-bipyridine ,  6,6'-Dimethyl-2,2'-bipyridine ,  4,4'-Dichloro-2,2'-bipyridine ,  4,4'-Dinitro-2,2'-bipyridine ,  4,4'-Di-tert-butyl-2,2'-bipyridine ,  3,3'-Dimethyl-2,2'-bipyridine ,  2,2′-Bi(4-dimethylaminopyridine) ,  4,4'-Dimethoxy-2,2'-bipyridine ,  2-(5-Methyl-2-thienyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborole ,  2-(5-Bromo-2-thienyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(5-Cyano-2-thienyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(5-Methoxy-2-furanyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(5-Methyl-2-furyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborole ,  2-[5-(Methoxycarbonyl)-2-furanyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(5-Methyl-1H-pyrrole-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-[5-(Methoxycarbonyl)-1H-pyrrole-2-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2,5-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborole-2-yl)thiophene ,  2,5-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)furan ,  2,5-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-1H-pyrrole

Terms in the title (8)： ビス ,  ほう素 ,  五員環 ,  イリジウム触媒 ,  ボリル化 ,  位置特異性 ,  当量 ,  室温