Art

J-GLOBAL ID：200902208197406269   Reference number：08A0580546

Mechanistic aspects of rearrangement of 16α-hydroxy-17-keto steroids to the 17β-hydroxy-16-keto isomers

16α-ヒドロキシ-17-ケトステロイドの17β-ヒドロキシ-16-ケト異性体への転位の機構面

Author (6)： NUMAZAWA Mitsuteru (Tohoku Pharmaceutical Univ., 4-1 Komatsushima-4-chome, Aoba-ku, Sendai 981-8558, JPN) ,  NAGAOKA Masao (Tohoku Pharmaceutical Univ., 4-1 Komatsushima-4-chome, Aoba-ku, Sendai 981-8558, JPN) ,  MATSUZAKI Hisao (Tohoku Pharmaceutical Univ., 4-1 Komatsushima-4-chome, Aoba-ku, Sendai 981-8558, JPN) ,  YAMASHITA Kouwa (Tohoku Pharmaceutical Univ., 4-1 Komatsushima-4-chome, Aoba-ku, Sendai 981-8558, JPN) ,  KOMATSU Sachiko (Tohoku Pharmaceutical Univ., 4-1 Komatsushima-4-chome, Aoba-ku, Sendai 981-8558, JPN) ,  OSAWA Yoshio (Hauptman-Woodward Medical Res. Inst., Inc.73 High street, Buffalo, NY 14203, USA)
Material： Steroids  (Steroids. Structure, Function and Regulation)
Volume： 73  Issue： 8  Page： 798-805  Publication year： Sep. 2008 
JST Material Number： C0103B  ISSN： 0039-128X  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *steroid ,  alicyclic alcohol ,  alicyclic ketone ,  *rearrangement reaction ,  oxygen 18 ,  deuteration ,  hydration ,  dewatering ,  carbonyl group ,  enolization ,  isotope effect ,  isomerization ,  isomer(molecule) ,  reaction intermediate ,  ground state ,  activation energy ,  rate theory ,  chemical synthesis ,  base catalytic reaction

JST classification (2)： Steroids  (CF10040O) ,  Regiochemistry of organic reaction  (CF02140G)

Substance index (2)： 16α-OH-DHEA ,  3β,17β-Dihydroxyandrost-5-en-16-one

Terms in the title (3)： 17-ケトステロイド ,  異性体 ,  転位