Art
J-GLOBAL ID：200902208355680349   Reference number：08A0170063

Total Synthesis of (+)-Achalensolide Based on the Rh(I)-Catalyzed Allenic Pauson-Khand-Type Reaction

Rh(I)触媒アレン性Pauson-Khand反応にもとづく(+)-アカレンソリドの全合成
Author (3)：
HIROSE Toshiyuki

About HIROSE Toshiyuki

(Kanazawa Univ., Kanazawa, JPN)

About Kanazawa Univ., Kanazawa, JPN

, 
MIYAKOSHI Naoki

About MIYAKOSHI Naoki

(Kanazawa Univ., Kanazawa, JPN)

About Kanazawa Univ., Kanazawa, JPN

, 
MUKAI Chisato

About MUKAI Chisato

(Kanazawa Univ., Kanazawa, JPN)

About Kanazawa Univ., Kanazawa, JPN


Material：
Journal of Organic Chemistry  (J Org Chem)

About Journal of Organic Chemistry


Volume： 73  Issue： 3  Page： 1061-1066  Publication year： Feb. 01, 2008 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)
Thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
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*metabolite

About metabolite

, 
*Stevia

About Stevia

, 
cycloalkene

About cycloalkene

, 
enone

About enone

, 
lactone

About lactone

, 
enyne

About enyne

, 
diyne

About diyne

, 
rhodium catalyst

About rhodium catalyst

, 
catalytic reaction

About catalytic reaction

, 
*total synthesis

About total synthesis

, 
Pauson-Khand reaction

About Pauson-Khand reaction


Semi thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
Stevia achalensis

About Stevia achalensis


JST classification (3)：
JST classification
Category name(code) classified by JST.
Condensed bicyclic carbocyclic compounds not containing 6-membered ring 
(CF06050K)

About Condensed bicyclic carbocyclic compounds not containing 6-membered ring

,  Condensed derivatives of furan 
(CF07073M)

About Condensed derivatives of furan

,  Other natural substances of biological origin 
(CF10090R)

About Other natural substances of biological origin

Substance index (12)：
Substance index
Chemical Substance indexed to the Article.
D-Ascorbic acid

About D-Ascorbic acid

, 
Achalensolide

About Achalensolide

, 
2,2-Dimethyl-4-[(2R)-oxirane-2-yl]-1,3-dioxolane

About 2,2-Dimethyl-4-[(2R)-oxirane-2-yl]-1,3-dioxolane

, 
(5R,6R)-5-(Methoxymethoxy)-6-(pivaloyloxy)-2,8-decadiyne-1-ol

About (5R,6R)-5-(Methoxymethoxy)-6-(pivaloyloxy)-2,8-decadiyne-1-ol

, 
(5R,6R)-3-Methyl-5-(methoxymethoxy)-6-(pivaloyloxy)-1,2-decadiene-8-yne

About (5R,6R)-3-Methyl-5-(methoxymethoxy)-6-(pivaloyloxy)-1,2-decadiene-8-yne

, 
(5R,6R)-3,8-Dimethyl-5-(pivaloyloxy)-6-(methoxymethoxy)-1,2,4,5,6,7-hexahydroazulene-2-one

About (5R,6R)-3,8-Dimethyl-5-(pivaloyloxy)-6-(methoxymethoxy)-1,2,4,5,6,7-hexahydroazulene-2-one

, 
(6R)-3,8-Dimethyl-6-(1-ethoxy-2-bromoethoxy)-1,2,6,7-tetrahydroazulene-2-one

About (6R)-3,8-Dimethyl-6-(1-ethoxy-2-bromoethoxy)-1,2,6,7-tetrahydroazulene-2-one

, 
(3aR)-5,8-Dimethyl-2,3,3aα,4,6,7,9,9aα-octahydroazuleno[6,5-b]furan-2,6-dione

About (3aR)-5,8-Dimethyl-2,3,3aα,4,6,7,9,9aα-octahydroazuleno[6,5-b]furan-2,6-dione

, 
(3aR)-5,8β-Dimethyl-2,3,3aα,4,6,7,7aα,8,9,9aα-decahydroazuleno[6,5-b]furan-2,6-dione

About (3aR)-5,8β-Dimethyl-2,3,3aα,4,6,7,7aα,8,9,9aα-decahydroazuleno[6,5-b]furan-2,6-dione

, 
(3aR)-5,8α-Dimethyl-2,3,3aα,4,6,7,7aβ,8,9,9aα-decahydroazuleno[6,5-b]furan-2,6-dione

About (3aR)-5,8α-Dimethyl-2,3,3aα,4,6,7,7aβ,8,9,9aα-decahydroazuleno[6,5-b]furan-2,6-dione

, 
(3aR)-3-Methylene-5,8β-dimethyl-6-(tert-butyldimethylsilyloxy)-2,3,3aα,4,6,7,7aα,8,9,9aα-decahydroazuleno[6,5-b]furan-2-one

About (3aR)-3-Methylene-5,8β-dimethyl-6-(tert-butyldimethylsilyloxy)-2,3,3aα,4,6,7,7aα,8,9,9aα-decahydroazuleno[6,5-b]furan-2-one

, 
(3aR)-3-(Hydroxymethyl)-5,8β-dimethyl-6-(tert-butyldimethylsilyloxy)-2,3,3aα,4,6,7,7aα,8,9,9aα-decahydroazuleno[6,5-b]furan-2-one

About (3aR)-3-(Hydroxymethyl)-5,8β-dimethyl-6-(tert-butyldimethylsilyloxy)-2,3,3aα,4,6,7,7aα,8,9,9aα-decahydroazuleno[6,5-b]furan-2-one

Terms in the title (5)：
Terms in the title
Keywords automatically extracted from the title.
Rh

About Rh

, 
触媒

About 触媒

, 
アレン

About アレン

, 
Pauson-Khand反応

About Pauson-Khand反応

, 
全合成

About 全合成


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