Art

J-GLOBAL ID：200902211212862463   Reference number：05A0294059

Ti-Crossed-Claisen Condensation between Carboxylic Esters and Acid Chlorides or Acids: A Highly Selective and General Method for the Preparation of Various β-Keto Esters

カルボン酸エステルと酸塩化物又は酸間のTi-交差Claisen縮合: 様々なβ-ケトエステルを調製するための高度に選択的で,一般的な方法

Author (4)： MISAKI T (Kwansei Gakuin Univ., Hyogo, JPN) ,  NAGASE R (Kwansei Gakuin Univ., Hyogo, JPN) ,  MATSUMOTO K (Kwansei Gakuin Univ., Hyogo, JPN) ,  TANABE Y (Kwansei Gakuin Univ., Hyogo, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 127  Issue： 9  Page： 2854-2855  Publication year： Mar. 09, 2005 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *Claisen condensation ,...

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JST classification (2)： Aliphatic carboxylic esters,anhydrides,acid halides,acyl peroxides  (CF03210P) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (52)： 1-Methyl-1H-imidazole ,  1,2-Dimethyl-1H-imidazole ,  1-Methyl-2-ethyl-1H-imidazole ,  1-Methyl-2-isopropyl-1H-imidazole ,  Propionic acid chloride ,  10-Undecenoic acid chloride ,  Cinnamic acid chloride ,  Benzyloxyacetic acid chloride ,  Isovaleric acid chloride ,  3,3-Dimethylbutyric acid chloride ,  3-Isobutenyl-2,2-dimethyl-1-cyclopropanecarboxylic acid chloride ,  Cyclohexanecarboxylic acid chloride ,  2-Ethylhexanoyl chloride ,  Hexanoic acid methyl ,  N-Acetylglycine methyl ester ,  3-Methylbutanoic acid methyl ,  Propionic acid methyl ,  4-Oxopentanoic acid ethyl ,  3-Phenylpropionic acid methyl ,  Acetic acid ethyl ,  3,3-Dimethyl-4-pentenoic acid methyl ,  Phenylacetic acid methyl ,  2-(Benzyloxy)acetic acid methyl ester ,  6-(Tosyloxy)hexanoic acid ethyl ester ,  N-Acetylmethionine methyl ester ,  2-Propanoylhexanoic acid methyl ester ,  2-Butyl-3-oxo-12-tridecenoic acid ,  2-(Acetylamino)-3-oxo-12-tridecenoic acid ,  2-Isopropyl-3-oxo-5-phenyl-4-pentenoic acid methyl ester ,  N-Acetyl-2-(benzyloxyacetyl)glycine methyl ester ,  2-(Acetylamino)-3-oxo-5-methylhexanoic acid methyl ester ,  2-(3,3-Dimethylbutyryl)hexanoic acid methyl ester ,  2-(2-Oxopropyl)-3-oxo-5-methylhexanoic acid ethyl ester ,  2-[2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropylcarbonyl]-3-phenylpropionic acid methyl ester ,  2-(Cyclohexylcarbonyl)hexanoic acid methyl ester ,  2-(Cyclohexylcarbonyl)-3,3-dimethyl-4-pentenoic acid methyl ester ,  2-Phenyl-3-oxo-3-cyclohexylpropionic acid methyl ester ,  (Benzyloxy)(cyclohexylcarbonyl)acetic acid methyl ester ,  2-(Cyclohexylcarbonyl)-6-(tosyloxy)hexanoic acid ethyl ester ,  (Acetylamino)(cyclohexylcarbonyl)acetic acid methyl ester ,  N-Acetyl-2-(cyclohexylcarbonyl)-L-methionine methyl ester ,  2-Butyl-3-oxo-4-ethyloctanoic acid methyl ester ,  Propionic acid ,  10-Undecenoic acid ,  Cyclohexanecarboxylic acid ,  2-Ethylhexanoic acid ,  2-Bromopropionic acid ,  (R)-2-(Benzyloxy)propanoic acid ,  2-(2-Bromopropanoyl)hexanoic acid methyl ester ,  2-[(R)-2-(Benzyloxy)propanoyl]hexanoic acid methyl ester ,  cis-Jasmone ,  Muscone

Terms in the title (8)： カルボン酸エステル ,  酸塩化物 ,  酸 ,  Ti ,  交差 ,  Claisen縮合 ,  ケトエステル ,  調製