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J-GLOBAL ID：200902212714109293   Reference number：03A0875810

A novel synthesis of α-hydroxy- and α,α′-dihydroxyketone from α-iodo and α,α′-diiodo ketone using photoirradiation.

光照射を使ったα-ヨードおよびα,α′-ジヨードケトンからのα-ヒドロキシ-及びα,α′-ジヒドロキシケトンの新規な合成

Author (6)： HORIUCHI C A (Rikkyo (St. Paul’s) Univ., Tokyo, JPN) ,  TAKEDA A (Rikkyo (St. Paul’s) Univ., Tokyo, JPN) ,  CHAI W (Rikkyo (St. Paul’s) Univ., Tokyo, JPN) ,  OHWADA K (Rikkyo (St. Paul’s) Univ., Tokyo, JPN) ,  JI S-J (Suzhou Univ., Jiangsu, CHN) ,  TAKAHASHI T T (Jikei Univ. School of Medicine, Tokyo, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 44  Issue： 52  Page： 9307-9311  Publication year： Dec. 22, 2003 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (2)： Photochemical reaction,radical reaction  (CF02090A) ,  Aliphatic ketones  (CF03190Q)

Substance index (54)： 2-Iodocyclohexanone ,  2-Iodocycloheptanone ,  2-Iodocyclooctanone ,  2-Iodocyclodecanone ,  2-Iodocyclododecanone ,  2-Iodocycloheptadecan-1-one ,  2-Hydroxycyclohexanone ,  2-Hydroxycycloheptanone ,  2-Hydroxycyclooctanone ,  Sebacoin ,  2-Hydroxycyclododecanone ,  2-Hydroxycypcloheptadecan-1-one ,  2-Iodotetralin-1-one ,  2-Hydroxytetralin-1-one ,  α-Iodopropiophenone ,  α-Bromopropiophenone ,  α-Hydroxypropiophenone ,  2-Iodobutyrylbenzene ,  α-Bromobutyrophenone ,  α-Hydroxybutyrophenone ,  3-Iodo-2-heptanone ,  3-Hydroxy-2-heptanone ,  α-Bromocamphor ,  (1R,4S)-1β,7,7-Trimethyl-3-hydroxybicyclo[2.2.1]heptane-2-one ,  2-Hydroxy-3-isopropyl-6-iodo-6-methyl-2-cyclohexene-1-one ,  2-Hydroxy-3,6-dimethyl-6-iodo-2-cyclohexene-1-one ,  1,3-Dihydroxy-p-mentha-3-ene-2-one ,  2,6-Dihydroxy-3,6-dimethyl-2-cyclohexene-1-one ,  2,4-Diiodo-3-pentanone ,  2,4-Dihydroxy-3-pentanone ,  3,5-Diiodo-4-heptanone ,  3,5-Dihydroxy-4-heptanone ,  4,6-Diiodo-5-nonanone ,  4,6-Dihydroxy-5-nonanone ,  5,7-Diiodoundecane-6-one ,  5,7-Dihydroxyundecane-6-one ,  2,4-Diiodoundecane-3-one ,  2,4-Dihydroxyundecane-3-one ,  1,3-Diiodo-2-hexanone ,  1,3-Dihydroxy-2-hexanone ,  1,3-Diiodo-2-heptanone ,  1,3-Dihydroxy-2-heptanone ,  2,7-Diiodocycloheptanone ,  2,7-Dihydroxycycloheptanone ,  2,12-Diiodocyclododecane-1-one ,  2,12-Dihydroxycyclododecane-1-one ,  (2R,3R)-2-Iodo-3-methoxybutanoic acid ethyl ester ,  (3R)-2-Hydroxy-3-methoxybutanoic acid ethyl ester ,  (2R,3R)-2-Iodo-3-ethoxybutanoic acid ethyl ester ,  (3R)-2-Hydroxy-3-ethoxybutanoic acid ethyl ester ,  (2R,3R)-2-Iodo-3-methoxy-3-phenylpropionic acid ethyl ester ,  (3R)-2-Hydroxy-3-methoxy-3-phenylpropionic acid ethyl ester ,  (2R,3R)-2-Iodo-3-ethoxy-3-phenylpropionic acid ethyl ester ,  (3R)-2-Hydroxy-3-ethoxy-3-phenylpropionic acid ethyl ester

Terms in the title (1)： 光照射