Art

J-GLOBAL ID：200902214911518386   Reference number：07A0084569

Preparation of 2-trimethylsilylmethyl-1-alkene; cross-coupling and protodesilylation sequence from 1,1-dibromo-1-alkene

2-トリメチルシリルメチル-1-アルケンの合成 1,1-ジブロモ-1-アルケンの逐次的な交差カップリング及びプロトン化脱シリル

Author (3)： UENISHI Jun'ichi (Kyoto Pharmaceutical Univ., Misasagi Yamashina, Kyoto 607-8412, JPN) ,  IWAMOTO Takuya (Kyoto Pharmaceutical Univ., Misasagi Yamashina, Kyoto 607-8412, JPN) ,  OHMI Masashi (Kyoto Pharmaceutical Univ., Misasagi Yamashina, Kyoto 607-8412, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 48  Issue： 7  Page： 1237-1240  Publication year： Feb. 12, 2007 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *organosilicon compound ,...
Semi thesaurus term： desilylation

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JST classification (2)： Organosilicon compounds  (CF08030C) ,  Platinum family element complexes  (CE01100E)

Substance index (31)： 1,1-Dibromo-4-phenyl-1-butene ,  1,1-Dibromo-1-dodecene ,  (2,2-Dibromovinyl)cyclohexane ,  1,1-Dibromo-3-phenyl-1-butene ,  β,β-Dibromostyrene ,  1-(Dibromomethylene)-4-tert-butylcyclohexane ,  1-(Trimethylsilyl)-2-(trimethylsilylmethyl)-5-phenyl-2-pentene ,  1-(Trimethylsilyl)-2-(trimethylsilylmethyl)-2-tridecene ,  1-Cyclohexyl-2-(trimethylsilylmethyl)-3-(trimethylsilyl)-1-propene ,  1-(Trimethylsilyl)-2-(trimethylsilylmethyl)-4-phenyl-2-pentene ,  1-Phenyl-2-(trimethylsilylmethyl)-3-(trimethylsilyl)-1-propene ,  1-[1-(Trimethylsilylmethyl)-2-(trimethylsilyl)ethylidene]-4-tert-butylcyclohexane ,  p-Toluenesulfonic acid・pyridinium ,  2-(Trimethylsilylmethyl)-5-phenyl-1-pentene ,  2-(Trimethylsilylmethyl)-1-tridecene ,  2-(Trimethylsilylmethyl)-3-cyclohexyl-1-propene ,  2-(Trimethylsilylmethyl)-4-phenyl-1-pentene ,  (2-Benzyl-2-propenyl)trimethylsilane ,  2-(4-tert-Butylcyclohexyl)-3-(trimethylsilyl)-1-propene ,  Benzaldehyde ,  Isobutyraldehyde ,  Benzaldehyde dimethyl acetal ,  1,1-Dimethoxy-2-methylpropane ,  Cyclohexanone ,  2-Cyclohexen-1-one ,  1,6-Diphenyl-3-methylene-1-hexanol ,  2-Methyl-4-methylene-7-phenyl-3-heptanol ,  1,6-Diphenyl-1-methoxy-3-methylenehexane ,  2-Methyl-3-methoxy-4-methylene-7-phenylheptane ,  1-(2-Methylene-5-phenylpentyl)cyclohexanol ,  3-(2-Methylene-5-phenylpentyl)cyclohexanone

Terms in the title (5)： アルケン ,  逐次 ,  交差カップリング ,  プロトン化 ,  脱シリル