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J-GLOBAL ID：200902216079396286   Reference number：03A0868397

Stereoselective generation of cis-2-lithio-3-CF₃-oxirane via CF₃-substituted β-oxido carbenoids. Highly stereoselective synthesis of CF₃-substituted tri- and tetrasubstituted oxiranes and tetrasubstituted alkenes

CF₃-置換β-オキシドカルベノイド経由cis-2-リチオ-3-CF₃-オキシランの立体選択的発生 CF₃-置換三及び四置換オキシラン及び四置換アルケンの高度に立体選択的な合成

Author (6)： SHIMIZU M (Kyoto Univ., Kyoto, JPN) ,  FUJIMOTO T (Kyoto Univ., Kyoto, JPN) ,  LIU X (Kyoto Univ., Kyoto, JPN) ,  MINEZAKI H (Kyoto Univ., Kyoto, JPN) ,  HATA T (Kyoto Univ., Kyoto, JPN) ,  HIYAMA T (Kyoto Univ., Kyoto, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 59  Issue： 49  Page： 9811-9823  Publication year： Dec. 01, 2003 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *oxygen heterocyclic compound ,...
Semi thesaurus term： oxirane

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JST classification (2)： Three-membered heterocyclic compounds  (CF07050R) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (21)： Butyl lithium ,  1,1-Dichloro-2-(trifluoromethyl)-4-phenylbutane-2-ol ,  (E)-1,1-Dichloro-2-(trifluoromethyl)4-phenyl-3-butene-2-ol ,  (3R,4S)-1-Phenyl-3-(trifluoromethyl)-3,4-epoxyoctane ,  (1E,3R,4S)-1-Phenyl-3-(trifluoromethyl)-3,4-epoxy-1-octene ,  (3R,4S)-1-Phenyl-3-(trifluoromethyl)-3,4-epoxy-1-octyne ,  (2R,3S)-1,1,1-Trifluoro-2,3-epoxy-2-phenylheptane ,  (1E,3R,4S)-1,4-Diphenyl-3,4-epoxy-3-(trifluoromethyl)-1-butene ,  (3S,4R)-1-Phenyl-3,4-epoxy-3-(trifluoromethyl)-4-methyl-1-octyne ,  (3S,4S)-1-Phenyl-3,4-epoxy-3-(trifluoromethyl)-4-methyl-1-octyne ,  (3R,4R)-1-Phenyl-3,4-epoxy-3-(trifluoromethyl)-4-(trimethylsilyl)-1-octyne ,  (3R,4S)-1-Phenyl-3,4-epoxy-3-(trifluoromethyl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-1-octyne ,  (3R,4R)-1-Phenyl-3,4-epoxy-3-(trifluoromethyl)-4-(hydroxydiphenylmethyl)-1-octyne ,  (3R,4R)-1-Phenyl-3,4-epoxy-3-(trifluoromethyl)-4-(hydroxydiphenylmethyl)octane ,  2-Methyl-3-(trifluoromethyl)-5-phenyl-2-pentene ,  (4E)-2-Methyl-3-(trifluoromethyl)-5-phenyl-2,4-pentadiene ,  2-Methyl-3-(trifluoromethyl)-5-phenyl-2-pentene-4-yne ,  (3Z)-1,6-Diphenyl-3-(trifluoromethyl)-4-butyl-3-hexene-1,5-diyne ,  (Z)-1,4-Diphenyl-3-(trifluoromethyl)-3-octene-1-yne ,  (3S,4R)-1-Phenyl-3,4-epoxy-3-(trifluoromethyl)-4-lithio-1-octyne ,  (3Z)-1-Phenyl-3-(trifluoromethyl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-3-octene-1-yne

Terms in the title (5)： 置換 ,  CIS ,  オキシラン ,  立体 ,  アルケン