Art

J-GLOBAL ID：200902217377682913   Reference number：07A1238088

Acceleration effect of allylic hydroxy group on ring-closing enyne metathesis of terminal alkynes: scope and application to the synthesis of isofagomine

アリル位のヒドロキシル基が末端アルキンの閉環エニンメタセシスに及ぼす加速効果 適応範囲とイソファゴミンの合成への応用

Author (5)： IMAHORI Tatsushi (Fac. of Pharmaceutical Sciences, Tohoku Pharmaceutical Univ., 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558, JPN) ,  OJIMA Hidetomo (Fac. of Pharmaceutical Sciences, Tohoku Pharmaceutical Univ., 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558, JPN) ,  TATEYAMA Hiroki (Fac. of Pharmaceutical Sciences, Tohoku Pharmaceutical Univ., 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558, JPN) ,  MIHARA Yukiko (Fac. of Pharmaceutical Sciences, Tohoku Pharmaceutical Univ., 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558, JPN) ,  TAKAHATA Hiroki (Fac. of Pharmaceutical Sciences, Tohoku Pharmaceutical Univ., 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 49  Issue： 2  Page： 265-268  Publication year： Jan. 07, 2008 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *enyne ,...
Semi thesaurus term： hydroxyl group ,...

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JST classification (3)： Pyridines  (CF07095Q) ,  Platinum family element complexes  (CE01100E) ,  Synthesis of drugs  (GV01030F)

Substance index (22)： Isofagomine ,  Ethylene ,  2-Vinyloxirane ,  Propargyl(2-hydroxy-3-butenyl)(tert-butoxycarbonyl)amine ,  1-(tert-Butoxycarbonyl)-3-vinyl-1,2,5,6-tetrahydropyridine-5-ol ,  1-(Propargyloxy)-3-butene-2-ol ,  1-Octene-7-yne-3-ol ,  4,4-Dimethyl-1-octene-7-yne-3-ol ,  Propargyl(2-hydroxy-3-butenyl)malonic acid di-tert-butyl ester ,  1-Heptene-6-yne-3-ol ,  4,4-Dimethyl-1-heptene-6-yne-3-ol ,  α-Vinyl-2-propargylbenzenemethanol ,  3,6-Dihydro-5-vinyl-2H-pyran-3-ol ,  3-Vinyl-2-cyclohexene-1-ol ,  3-Vinyl-6,6-dimethyl-2-cyclohexene-1-ol ,  3-Vinyl-5-hydroxy-3-cyclohexene-1,1-dicarboxylic acid di-tert-butyl ester ,  3-Vinyl-2-cyclopentene-1-ol ,  3-Vinyl-5,5-dimethyl-2-cyclopentene-1-ol ,  1,4-Dihydro-3-vinylnaphthalene-1-ol ,  1-(tert-Butoxycarbonyl)-3-(tert-butyldimethylsiloxy)-5-(1,2-dihydroxyethyl)-1,2,3,6-tetrahydropyridine ,  1-(tert-Butoxycarbonyl)-5-(tert-butyldimethylsiloxy)-1,2,5,6-tetrahydropyridine-3-methanol ,  (3R)-1-(tert-Butoxycarbonyl)-4β-hydroxy-5-(tert-butyldimethylsiloxy)piperidine-3α-methanol

Terms in the title (8)： ヒドロキシル基 ,  末端アルキン ,  閉環 ,  エニンメタセシス ,  加速 ,  適応 ,  イソファゴミン ,  応用