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J-GLOBAL ID：200902218367093142   Reference number：04A0027168

Palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with vinyl triflates β-substituted by a carbonyl group: efficient synthesis of β-boryl-α,β-unsaturated carbonyl compounds and their synthetic utility

カルボニル基によってβ-置換されたビニルトリフラートとビス(ピナコラト)二ほう素とのパラジウム触媒交差カップリング反応 β-ボリル-α,β-不飽和カルボニル化合物の効率的合成とこれらの合成的有用性

Author (4)： ISHIYAMA T (Hokkaido Univ., Sapporo, JPN) ,  TAKAGI J (Hokkaido Univ., Sapporo, JPN) ,  KAMON A (Hokkaido Univ., Sapporo, JPN) ,  MIYAURA N (Hokkaido Univ., Sapporo, JPN)
Material： Journal of Organometallic Chemistry  (J Organomet Chem)
Volume： 687  Issue： 2  Page： 284-290  Publication year： Dec. 07, 2003 
JST Material Number： B0412C  ISSN： 0022-328X  Document type： Article
Article type： 原著論文  Country of issue： Netherlands (NLD)  Language： ENGLISH (EN)

Thesaurus term： palladium catalyst ,...

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JST classification (2)： Organoboron compounds  (CF08020R) ,  Catalytic reactions in general  (CB06080F)

Substance index (15)： Bis(pinacolato)diboron ,  2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-cyclopentene-1-carboxylic acid ethyl ester ,  2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-cyclohexene-1-carboxylic acid ethyl ester ,  2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-cycloheptene-1-carboxylic acid ethyl ester ,  2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-cyclooctene-1-carboxylic acid ethyl ester ,  N,N-Diethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-1-cyclohexene-1-carboxamide ,  2-Methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-2-cyclopentene-1-one ,  2-Methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-2-cyclohexene-1-one ,  3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-5,5-dimethyl-2-cyclohexene-1-one ,  (E)-3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-2-butenoic acid ethyl ester ,  (E)-N,N-Diethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-2-butenamide ,  (E)-3-[2-(Ethoxycarbonyl)-1-cyclohexenyl]-2-butenoic acid ethyl ester ,  (αE)-β,2-Dimethyl-3-oxo-1-cyclohexene-1-acrylic acid ethyl ester ,  (E)-3-Methyl-6-oxo-2-heptenoic acid ethyl ester ,  (E)-3-(3-Oxocyclohexyl)-2-butenoic acid ethyl ester

Terms in the title (9)： カルボニル基 ,  置換 ,  ビス ,  ほう素 ,  パラジウム触媒 ,  交差カップリング反応 ,  不飽和 ,  カルボニル化合物 ,  有用性