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J-GLOBAL ID：200902220012960168   Reference number：07A1215866

3-Iodo-3-trimethylsilylpropenal as a Useful Unit for Pinacol Coupling and Subsequent Functional Group Transformations

ピナコールカップリングとその後の官能基変換に有用なユニットとしての3-ヨード-3-トリメチルシリルプロペナール

Author (4)： SHIMIZU Makoto (Dep. of Chemistry for Materials, Graduate School of Engineering, Mie Univ.) ,  OKIMURA Hisashi (Dep. of Chemistry for Materials, Graduate School of Engineering, Mie Univ.) ,  MANABE Nobuyuki (Dep. of Chemistry for Materials, Graduate School of Engineering, Mie Univ.) ,  HACHIYA Iwao (Dep. of Chemistry for Materials, Graduate School of Engineering, Mie Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 37  Issue： 1  Page： 28-29 (J-STAGE)  Publication year： 2008 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (1)： Organosilicon compounds  (CF08030C)

Substance index (13)： (Z)-3-Iodo-3-(trimethylsilyl)propenal ,  rac-(1Z,3R^*,4R^*,5Z)-1,6-Diiodo-1,6-bis(trimethylsilyl)-1,5-hexadiene-3,4-diol ,  4α,5β-Bis[(Z)-2-iodo-2-(trimethylsilyl)vinyl]-2,2-dimethyl-1,3-dioxolane ,  3,3′-(2,2-Dimethyl-1,3-dioxolane-4α,5β-diyl)bis[(E)-1-(4-chlorophenyl)-2-iodo-2-propene-1-ol] ,  3,3′-(2,2-Dimethyl-1,3-dioxolane-4α,5β-diyl)bis[(E)-1-phenyl-2-iodo-2-propene-1-ol] ,  3,3′-(2,2-Dimethyl-1,3-dioxolane-4α,5β-diyl)bis[(E)-1-(4-methoxyphenyl)-2-iodo-2-propene-1-ol] ,  1,1′-(2,2-Dimethyl-1,3-dioxolane-4α,5β-diyl)bis[(1Z,4Z)-2-iodo-5-chloro-6,6-dimethyl-1,4-heptadiene-3-ol] ,  1,1′-(2,2-Dimethyl-1,3-dioxolane-4α,5β-diyl)bis[(1Z,4E)-2-iodo-5-phenyl-1,4-pentadiene-3-ol] ,  1,1′-(2,2-Dimethyl-1,3-dioxolane-4α,5β-diyl)bis[(1Z,4E)-2-iodo-1,4-octadiene-3-ol] ,  1,1′-(2,2-Dimethyl-1,3-dioxolane-4α,5β-diyl)bis[(Z)-2-iodo-5-phenyl-1-pentene-4-yne-3-ol] ,  3,3′-(2,2-Dimethyl-1,3-dioxolane-4α,5β-diyl)bis[(E)-1-cyclohexyl-2-iodo-2-propene-1-ol] ,  3,3′-(2,2-Dimethyl-1,3-dioxolane-4α,5β-diyl)bis[(E)-1-(4-chlorophenyl)-2-bromo-2-propene-1-ol] ,  3,3′-(2,2-Dimethyl-1,3-dioxolane-4α,5β-diyl)bis[(E)-1-phenyl-2-bromo-2-propene-1-ol]

Reference (23)：

• 1) a) R. Hayakawa, M. Shimizu, Chem. Lett. 2000, 724.
•  b) M. Shimizu, H. Goto, R. Hayakawa, Org. Lett. 2002, 4, 4097.
• 2) a) J. Yoshida, K. Tamao, T. Kakui, M. Kumada, Tetrahedron Lett. 1979, 20, 1141.
•  b) T. Hiyama, Y. Hatanaka, Pure Appl. Chem. 1994, 66, 1471.
•  c) K. A. Horn, Chem. Rev. 1995, 95, 1317.

Terms in the title (2)： ピナコールカップリング ,  官能基