Art

J-GLOBAL ID：200902220525214402   Reference number：09A0450853

Iron-Catalyzed Chemoselective ortho Arylation of Aryl Imines by Directed C-H Bond Activation

直接C-H結合活性化を経るアリールイミン類の鉄触媒による化学選択的orthoアリール化

Author (4)： YOSHIKAI Naohiko (Univ. Tokyo, Tokyo, JPN) ,  MATSUMOTO Arimasa (Univ. Tokyo, Tokyo, JPN) ,  NORINDER Jakob (Univ. Tokyo, Tokyo, JPN) ,  NAKAMURA Eiichi (Univ. Tokyo, Tokyo, JPN)
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 48  Issue： 16  Page： 2925-2928  Publication year： 2009 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *aromatic ketone ,  phenyl group ,  regiospecific reaction ,  iron catalyst ,  arylation ,  C-H bond ,  chemical synthesis ,  activation ,  zinc chloride ,  Grignard reagent ,  aliphatic chlorine compound ,  azomethine ,  aliphatic ketone ,  diketone ,  biaryls
Semi thesaurus term： biaryl ,  C-H bond activation

JST classification (2)： Aromatic monocyclic ketones  (CF05170I) ,  Regiochemistry of organic reaction  (CF02140G)

Substance index (23)： 4,4'-Di-tert-butyl-2,2'-bipyridine ,  N,N,N',N'-Tetramethylethylenediamine ,  Acetylacetone ,  Phenylmagnesium bromide ,  N-(4-Methoxyphenyl)-1-(2-biphenylyl)ethanimine ,  N-Phenyl-1-(2-biphenylyl)ethanimine ,  α-Methyl-N-(4-methylphenyl)biphenyl-2-methaneimine ,  2-Acetylbiphenyl ,  2-Propanoylbiphenyl ,  8-Phenyltetralin-1-one ,  2-Acetyl-3-phenylthiophene ,  2-Acetyl-5-chlorobiphenyl ,  2-Acetyl-4-chlorobiphenyl ,  2-Acetyl-4-bromobiphenyl ,  2-Acetyl-5-(trifluoromethylsulfonyloxy)biphenyl ,  2-Acetyl-5-(tosyloxy)biphenyl ,  2-Acetyl-5-methoxybiphenyl ,  2-Acetyl-5-(trifluoromethyl)biphenyl ,  4-Methoxyphenylboronic acid ,  4-Methoxy-4′-acetyl-1,1′:3′,1′′-terbenzene ,  2-Acetyl-5-(trifluoromethylsulfonyloxy)-4′-methoxybiphenyl ,  2-Acetyl-5-(trifluoromethylsulfonyloxy)-4′-tert-butylbiphenyl ,  1,2-Dichloro-2-methylpropane

Terms in the title (5)： C-H結合 ,  活性化 ,  鉄触媒 ,  化学 ,  アリール化